Synthesis and Catalytic Activity of Dinuclear Rare-Earth Metal Complexes with Nitrogen-Containing Bridged Dipyrrolyl Ligand towards Ring-Opening Polymerization of e-Caprolactone

doi:10.6023/cjoc201908010

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (3): 801-805.DOI: 10.6023/cjoc201908010 Previous Articles Next Articles

含氮原子桥联吡咯基稀土金属双核配合物的合成及催化e-己内酯的开环聚合反应

吴杰, 张秀丽, 张丽军, 韦芸, 周双六

安徽师范大学化学与材料科学学院功能分子固体教育部重点实验室分子基材料安徽省重点实验室安徽芜湖 241002

收稿日期:2019-08-06 修回日期:2019-10-13 发布日期:2019-11-01
通讯作者: 张丽军, 周双六 E-mail:zljun@ahnu.edu.cn;slzhou@ahnu.edu.cn
基金资助:
国家自然科学基金（Nos.21672004，21602004）资助项目.

Synthesis and Catalytic Activity of Dinuclear Rare-Earth Metal Complexes with Nitrogen-Containing Bridged Dipyrrolyl Ligand towards Ring-Opening Polymerization of e-Caprolactone

Wu Jie, Zhang Xiuli, Zhang Lijun, Wei Yun, Zhou Shuangliu

Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000

Received:2019-08-06 Revised:2019-10-13 Published:2019-11-01
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21672004, 21602004).

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Abstract

Reaction of RE(CH₂SiMe₃)₃(THF)₂ with 1.5 equiv. of (C₄H₃NHCH₂)₂NCH₃ (1) in toluene gave nitrogen-containing bridged dipyrrolyl dinuclear rare-earth metal complexes[η¹:η¹:η¹-(C₄H₃NCH₂)₂NCH₃]RE{m-η⁵:η¹:η⁵:η¹:η¹-(C₄H₃NCH₂)₂N-CH₃}RE[η¹:η¹:η¹-(C₄H₃NCH₂)₂NCH₃](THF)[RE=Y (2), Er (3), Yb (4)]. All complexes were fully characterized by spectroscopic methods and elemental analyses. The structures of complexes 2 and 4 were further determined by single-crystal X-ray diffraction. The catalytic properties of rare-earth metal complexes on the ring-opening polymerization of e-caprolactone have been studied.

Key words: rare-earth metal, complex, e-caprolactone, ring-opening polymerization

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Wu Jie, Zhang Xiuli, Zhang Lijun, Wei Yun, Zhou Shuangliu. Synthesis and Catalytic Activity of Dinuclear Rare-Earth Metal Complexes with Nitrogen-Containing Bridged Dipyrrolyl Ligand towards Ring-Opening Polymerization of e-Caprolactone[J]. Chinese Journal of Organic Chemistry, 2020, 40(3): 801-805.

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含氮原子桥联吡咯基稀土金属双核配合物的合成及催化e-己内酯的开环聚合反应

Synthesis and Catalytic Activity of Dinuclear Rare-Earth Metal Complexes with Nitrogen-Containing Bridged Dipyrrolyl Ligand towards Ring-Opening Polymerization of e-Caprolactone

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