Recent Advance in the Transition-Metal-Catalyzed Carbene Insertion Reactionsof Si—H Bond

doi:10.6023/cjoc201911009

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (4): 873-885.DOI: 10.6023/cjoc201911009 Previous Articles Next Articles

过渡金属催化卡宾对Si―H键的插入反应研究进展

张慧苗^a, 李灵芝^a, 沈方旗^b, 蔡涛^a, 沈润溥^a

a 绍兴文理学院化学化工学院浙江绍兴 312000;
b 西北师范大学化学化工学院兰州 730070

收稿日期:2019-11-06 修回日期:2019-12-04 发布日期:2019-12-19
通讯作者: 蔡涛 E-mail:cait361@163.com
基金资助:
绍兴文理学院科研启动基金（No.20185019）资助项目.

Recent Advance in the Transition-Metal-Catalyzed Carbene Insertion Reactionsof Si—H Bond

Zhang Huimiao^a, Li Lingzhi^a, Shen Fangqi^b, Cai Tao^a, Shen Runpu^a

a College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing, Zhejiang 312000;
b College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Received:2019-11-06 Revised:2019-12-04 Published:2019-12-19
Supported by:
Project supported by the Youth Foud of Shaoxing University (No. 20185019).

Organosilicon compounds have been widely used in organic synthesis, biomedicine, material science and other fields. The development of simple and efficient C——Si bond construction methodology has attracted extensive attention from scientists. Transition-metal-catalyzed carbene insertion reaction of Si——H bond is one of the important methods to form C——Si bond. It not only has the advantages of simple operation, mild reaction conditions and high atom economy, but also can be used to synthesize various chiral organosilanes with high enantioselectivity through the regulation of chiral ligands. In recent years, achieved rapid development has been in this field, and various new carbene precursors and metal catalytic systems have been emerged. According to the group of transition metal elements, recent advance in the iron, copper, zinc, ruthenium, rhodium, palladium, silver, iridium and gold catalyzed carbene insertion reactions of Si——H bond since 2012 is reviewed in five parts.

Key words: transition metal catalysis, metal carbene, Si—H bond insertion, C—Si bond formation, organosilane

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Zhang Huimiao, Li Lingzhi, Shen Fangqi, Cai Tao, Shen Runpu. Recent Advance in the Transition-Metal-Catalyzed Carbene Insertion Reactionsof Si—H Bond[J]. Chinese Journal of Organic Chemistry, 2020, 40(4): 873-885.

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过渡金属催化卡宾对Si―H键的插入反应研究进展

Recent Advance in the Transition-Metal-Catalyzed Carbene Insertion Reactionsof Si—H Bond

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