Researches on the Hydrodehalogenation of o-Triazole Aryl Halides in the System of Pd/C and Et3N

doi:10.6023/cjoc201912010

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (5): 1372-1377.DOI: 10.6023/cjoc201912010 Previous Articles Next Articles

钯碳/三乙胺体系中邻位三唑取代芳基卤化物的脱卤氢化反应研究

邱会华, 林白银, 周鹏, 张建涛, 刘卫兵

广东石油化工学院化学学院广东茂名 525000

收稿日期:2019-12-08 修回日期:2020-01-04 发布日期:2020-01-15
通讯作者: 周鹏 E-mail:zzd83@aliyun.com
基金资助:
国家自然科学基金（No.21602035）、广东省自然科学基金（No.2016A030307030）和广东石油化工学院（No.519124）资助项目.

Researches on the Hydrodehalogenation of o-Triazole Aryl Halides in the System of Pd/C and Et₃N

Qiu Huihua, Lin Baiyin, Zhou Peng, Zhang Jiantao, Liu Weibing

College of Chemistry, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000

Received:2019-12-08 Revised:2020-01-04 Published:2020-01-15
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21602035), the Natural Science Foundation of Guangdong Province (No. 2016A030307030) and the Program for Innovative Research Team of Guangdong University of Petrochemical Technology (No. 519124).

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Abstract

The hydrodehalogenation of halogenated organic compounds which have brought serious pollution to the environment can not only transform them into other usefull chemicals, but also reduce their pollution in the field of environment. A Pd-catalyzed hydrodehalogenation of o-triazole aryl halides is introduced, taking Pd/C as catalyst and Et₃N as base, reductant and hydrogen source. This strategy is highlighted by appealing features such as simple reaction condition, recyclable catalyst, and good yield etc.

Key words: aryl halides, hydrodehalogenation, Pd catalyzed, triazole, triethylamine

Cite this article

Qiu Huihua, Lin Baiyin, Zhou Peng, Zhang Jiantao, Liu Weibing. Researches on the Hydrodehalogenation of o-Triazole Aryl Halides in the System of Pd/C and Et₃N[J]. Chinese Journal of Organic Chemistry, 2020, 40(5): 1372-1377.

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钯碳/三乙胺体系中邻位三唑取代芳基卤化物的脱卤氢化反应研究

Researches on the Hydrodehalogenation of o-Triazole Aryl Halides in the System of Pd/C and Et₃N

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