Application of tert-Butanesulfinamide in Total Synthesis of Natural Products

doi:10.6023/cjoc202006024

Abstract

The formation of chiral amine intermediates with chiral tert-butanesulfinamide and their applications in asymmetric natural product synthesis in recent years are summarized. tert-Butanesulfinamide has attracted wide attention from chemists because it is stable, commercially available with reasonable price, ease to use, and usually induces high diastereoselectivity in the reactions involved. This review is divided into two sections, including the addition of nucleophiles to N-tert-butanesulfinyl imines and the addition of N-tert-butanesulfinyl metalloenamines to electrophiles.

Key words: tert-butanesulfinamide, chiral amine, total synthesis

Cite this article

Li Ying, Ma Zhiqiang, Xu Xuetao. Application of tert-Butanesulfinamide in Total Synthesis of Natural Products[J]. Chinese Journal of Organic Chemistry, 2020, 40(12): 3991-4014.

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