Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (4): 1033-1060.DOI: 10.6023/cjoc202110026 Previous Articles     Next Articles

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过渡金属催化偕二溴烯烃衍生物的偶联反应

梁陆祺a,b, 张立志b,*(), 彭永利a,*(), 刘会a,b,*()   

  1. a 武汉工程大学材料科学与工程学院 武汉 430205
    b 山东理工大学化学与工程学院 山东淄博 255049
  • 收稿日期:2021-10-19 修回日期:2021-12-03 发布日期:2021-12-22
  • 通讯作者: 张立志, 彭永利, 刘会
  • 基金资助:
    国家自然科学基金(22078178); 山东省青年创新团队引育计划资助项目.

Transition-Metal Catalyzed Coupling Reactions of gem-Dibromovinyl Derivatives

Luqi Lianga,b, Lizhi Zhangb(), Yongli Penga(), Hui Liua,b()   

  1. a School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205
    b School of Chemical Engineering, Shandong University of Technology, Zibo, Shandong 255049
  • Received:2021-10-19 Revised:2021-12-03 Published:2021-12-22
  • Contact: Lizhi Zhang, Yongli Peng, Hui Liu
  • Supported by:
    National Natural Science Foundation of China(22078178); Youth Innovative Talents Attracting and Cultivating Plan of Colleges and Universities in Shandong Province.

gem-Dibromovinyl derivatives are valuable synthetic tools in organic chemistry, which have been widely applied in the construction of founctionalized molecules. In the past few years, metal-catalyzed (such as Pd, Cu, Ag, Au and Ni) transformations with gem-dibromovinyl derivatives have been developed and become a powerful tool for the synthesis of alkynes, chromenes, indoles, benzindole, benzothiophene and other benzo-fused heterocycles with important physiological activity. The progresses in transition-metal-catalyzed transformations of gem-dibromoviny derivatives since 2013 are summarized.

Key words: gem-dibromovinyl derivative, alkynyl intermediate, transition metal catalysis, coupling reaction