Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (6): 1778-1785.DOI: 10.6023/cjoc202111031 Previous Articles Next Articles
ARTICLES
李芳绍, 肖晶*(), 吴小芳, 王晓熠, 邓金凤, 唐子龙*()
收稿日期:
2021-11-22
修回日期:
2022-02-08
发布日期:
2022-02-25
通讯作者:
肖晶, 唐子龙
基金资助:
Fangshao Li, Jing Xiao(), Xiaofang Wu, Xiaoyi Wang, Jinfeng Deng, Zilong Tang()
Received:
2021-11-22
Revised:
2022-02-08
Published:
2022-02-25
Contact:
Jing Xiao, Zilong Tang
Supported by:
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Fangshao Li, Jing Xiao, Xiaofang Wu, Xiaoyi Wang, Jinfeng Deng, Zilong Tang. Metal-Free Formation of 2-Substitued Benzoxazoles with Amides and Esters[J]. Chinese Journal of Organic Chemistry, 2022, 42(6): 1778-1785.
Entry | PCl3/equiv. | V(H2O)/μL | Solvent | Yieldb/% |
---|---|---|---|---|
1 | 1.2 | 50 | DCE | 52 |
2 | 1.0 | 50 | DCE | 82 |
3 | 0.8 | 50 | DCE | 70 |
4 | 1.0 | 65 | DCE | 49 |
5 | 1.0 | 35 | DCE | 46 |
6 | 1.0 | 0 | DCE | 0 |
7 | 1.0 | 50 | CH3CN | 54 |
8 | 1.0 | 50 | Toluene | 65 |
9 | 1.0 | 50 | PhCl | 60 |
10 | 1.0 | 50 | DMF | Trace |
11 | 1.0 | 50 | DCE | 62c |
12 | 1.0 | 50 | DCE | 21d |
13 | 1.0 | 50 | DCE | 66e |
14 | 0 | 50 | DCE | 0 |
15 | 1.0 | 50 | DCE | 43f |
Entry | PCl3/equiv. | V(H2O)/μL | Solvent | Yieldb/% |
---|---|---|---|---|
1 | 1.2 | 50 | DCE | 52 |
2 | 1.0 | 50 | DCE | 82 |
3 | 0.8 | 50 | DCE | 70 |
4 | 1.0 | 65 | DCE | 49 |
5 | 1.0 | 35 | DCE | 46 |
6 | 1.0 | 0 | DCE | 0 |
7 | 1.0 | 50 | CH3CN | 54 |
8 | 1.0 | 50 | Toluene | 65 |
9 | 1.0 | 50 | PhCl | 60 |
10 | 1.0 | 50 | DMF | Trace |
11 | 1.0 | 50 | DCE | 62c |
12 | 1.0 | 50 | DCE | 21d |
13 | 1.0 | 50 | DCE | 66e |
14 | 0 | 50 | DCE | 0 |
15 | 1.0 | 50 | DCE | 43f |
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