Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (3): 293-296. Previous Articles     Next Articles

3,6-二甲基-9-芳基-1,8-二氧代-2,7,10-三氧杂蒽的合成及晶体结构

高原*, 刘剑洪, 黄毅, 张雪利, 张伟华   

  1. 深圳大学失范学院化学系 深圳 518060
  • 收稿日期:2003-05-12 修回日期:2003-08-29 接受日期:2003-09-26 发布日期:2022-09-20
  • 基金资助:
    国家自然科学基金(No. 20072025)资助项目

Synthesis and Crystal Structure of 9-Aryl-3,6-dimethyl- 1,8-dioxo-2,7,10-trioxanthene

GAO, Yuan*, LIU, Jiang-Hong, HUANG, Yi, ZHANG, Xue-Li, ZHANG, Wei-Hua   

  1. Department of Chemistry, Normal College, Shenzhen University, Shenzhen 518060
  • Received:2003-05-12 Revised:2003-08-29 Accepted:2003-09-26 Published:2022-09-20
  • Contact: *E-mail: zengwei109@hotmail.com

A series of 9-aryl-3,6-dimethyl-1,8-dioxo-2,7,10-trioxanthenes were synthesized by the reaction of aromatic aldehydes with 4-hydroxyl-6-methyl-2-pyranone in acetic anhydride. The structure of the product was determinedby IR, 1H NMR, elemental analysis and X-ray diffraction analysis. A possible mechanism for this reaction is postulated.

Key words: aromatic aldehyde, pyranone, trioxanthene, crystal structure