Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (7): 745-752. Previous Articles     Next Articles

盒状主体缺电子联吡啶大环的性质、应用和制备

何光裕a, 孙小强*,a, 汪信b   

  1. a江苏工业学院化学工程系 精细化工重点实验室 常州 213016
    b南京理工大学化工学院 南京 210094
  • 收稿日期:2003-06-17 修回日期:2003-09-23 接受日期:2003-11-25 发布日期:2022-09-20
  • 通讯作者: *E-mail: xqsun@jpu.edu.cn
  • 基金资助:
    国家自然科学基金(No. 21071021)资助项目

Properties, Applications and Synthesis of Cyclophane-Like Tetracation Cyclobis(paraquat-p-phenylene)

HE, Guang-Yua, SUN, Xiao-Qiang*,a, WANG, Xinb   

  1. a Department of Chemical Engineering, Key Laboratory of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016
    b Institute of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094
  • Received:2003-06-17 Revised:2003-09-23 Accepted:2003-11-25 Published:2022-09-20

Tetracation cyclobis(paraquat-p-phenylene) is a cyclophane-like molecular receptor, which contains π-electron-deficient bipyridinium units for face-to-face complexation with π-electron-rich hydroquinone units. Its synthetic strategies, structural characters, properties and applicationsto the self-assembly of rotaxanes and catenanes are reviewed.

Key words: tetracation cyclobis(paraquat-p-phenylene), catenane, rotaxane, pseudorotaxane