Enhancement Effect of Lithium Perchlorate on the Esterification Catalyzed by Yb(NTf2)3-Resin Catalyst

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (7): 778-782. Previous Articles Next Articles

高氯酸锂促进的固体酸催化酯化反应

王丽琼, 聂进^*, 李小永, 张正波, 尹飞

华中科技大学化学系武汉 430074

收稿日期:2003-06-23 修回日期:2004-01-07 接受日期:2004-02-09 发布日期:2022-09-20
通讯作者: ^*E-mail: niejin@mail.hust.edu.cn

Enhancement Effect of Lithium Perchlorate on the Esterification Catalyzed by Yb(NTf₂)₃-Resin Catalyst

WANG, Li-Qiong, NIE, Jin^*, LI, Xiao-Yong, ZHANG, Zheng-Bo, YIN, Fei

Department of Chemistry, Huazhong University of Technology and Science, Wuhan430074

Received:2003-06-23 Revised:2004-01-07 Accepted:2004-02-09 Published:2022-09-20

Abstract

A novel solid acid catalyst was prepared by supporting Yb(NTf₂)₃ on NKC-9 resin and the new catalyst showed higher catalytic activity inesterification reactions compared with that of Yb(NTf₂)₃ as homogenous catalyst. When lithium perchlorate was added together with this solid acid catalyst, the esterification of benzoic acid with alcohols was significantly accelerated. The effects of reaction time, temperature, Yb(NTf₂)₃ loadings and LiClO₄ dosage upon esterification were also investigated. Under the optimum conditions: supported resin 30 wt%, Yb(NTf₂)₃ 0.8 mol%, LiClO₄ 58 mol%, acid∶alcohol (molar ratio)=1∶7 and reflux for 2 h, the yield of ethyl benzoate was over 99%. A tentative study of the LiClO₄ acceleration effect was made through comparison of different catalysts.

Key words: Yb(NTf₂)₃, lithium perchlorate, solid acid, resin, esterification

Cite this article

WANG, Li-Qiong, NIE, Jin, LI, Xiao-Yong, ZHANG, Zheng-Bo, YIN, Fei. Enhancement Effect of Lithium Perchlorate on the Esterification Catalyzed by Yb(NTf₂)₃-Resin Catalyst[J]. Chinese Journal of Organic Chemistry, 2004, 24(7): 778-782.

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高氯酸锂促进的固体酸催化酯化反应

Enhancement Effect of Lithium Perchlorate on the Esterification Catalyzed by Yb(NTf₂)₃-Resin Catalyst

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