Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (6): 1987-1997.DOI: 10.6023/cjoc202312023 Previous Articles Next Articles
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田永盛a, 魏斓枫c, 黄嘉为a, 韦玉a, 徐亮a,*(), 刘帅b,*()
收稿日期:
2023-12-24
修回日期:
2024-01-17
发布日期:
2024-02-19
基金资助:
Yongsheng Tiana, Lanfeng Weic, Jiawei Huanga, Yu Weia, Liang Xua,*(), Shuai Liub,*()
Received:
2023-12-24
Revised:
2024-01-17
Published:
2024-02-19
Contact:
* Supported by:
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Yongsheng Tian, Lanfeng Wei, Jiawei Huang, Yu Wei, Liang Xu, Shuai Liu. Deboronative Selenylation, Bromination, or Hydroxylation of Organic Boronic Acids Facilitated by Tetrabutylammonium Tribromide under Transition Metal-Free Conditions[J]. Chinese Journal of Organic Chemistry, 2024, 44(6): 1987-1997.
Entry | Variation from the standard conditions | Yieldb/% |
---|---|---|
1 | None | 92 |
2 | Without TBATB | N.R.c |
3 | TBATB (10 mol%) | 65 |
4 | Without light (in dark) | 90 |
5 | Without O2 (with Ar) | 87 |
6 | DMF instead of DMSO | 31 |
7 | MeCN instead of DMSO | 17 |
8 | MeOH instead of DMSO | 29 |
9 | Room temperature | 47 |
10 | 80 ℃ instead of 100 ℃ | 79 |
11 | 90 ℃ instead of 100 ℃ | 85 |
12 | 10 h instead of 12 h | 86 |
13 | 11 h instead of 12 h | 90 |
Entry | Variation from the standard conditions | Yieldb/% |
---|---|---|
1 | None | 92 |
2 | Without TBATB | N.R.c |
3 | TBATB (10 mol%) | 65 |
4 | Without light (in dark) | 90 |
5 | Without O2 (with Ar) | 87 |
6 | DMF instead of DMSO | 31 |
7 | MeCN instead of DMSO | 17 |
8 | MeOH instead of DMSO | 29 |
9 | Room temperature | 47 |
10 | 80 ℃ instead of 100 ℃ | 79 |
11 | 90 ℃ instead of 100 ℃ | 85 |
12 | 10 h instead of 12 h | 86 |
13 | 11 h instead of 12 h | 90 |
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