Synthesis of cis-alkene with electron-withdrawing groups via photocatalytic isomerization

doi:10.6023/cjoc202505010

Chinese Journal of Organic Chemistry Previous Articles Next Articles

光催化异构化合成含吸电子取代基顺式烯烃研究

林如海, 毛伟^*, 涂东怀, 董兴宗, 马辉, 吕剑^*

西安近代化学研究所氟氮化工新材料全国重点实验室西安 710065

收稿日期:2025-05-08 修回日期:2025-06-11
基金资助:
国家自然基金（No. 22072112）; 中央引导地方科技发展资金（No. 2022ZY2-JCYJ-02）; 陕西省重点研发计划（No. 2021ZDLGY13-09）

Synthesis of cis-alkene with electron-withdrawing groups via photocatalytic isomerization

Lin Ruhai, Mao Wei^*, Tu Donghuai, Dong Xingzong, Ma Hui, Lu Jian^*

Xi’an Modern Chemistry Research Institute, State Key Laboratory of Fluorine & Nitrogen Chemical, Xi’an 710065

Received:2025-05-08 Revised:2025-06-11
Contact: ^*E-mail: hz_mw@163.com; lujian204@263.net.

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Abstract

We report a method for the photocatalytic isomerization synthesis of cis-olefins containing electron-withdrawing groups. The target cis-alkene was synthesized via photocatalytic isomerization using Ir(ppy)₃ as the photosensitizer and 365 nm UV light as the excitation source. This method features mild reaction conditions, high safety, great selectivity, and broad substrate applicability, providing a valuable strategy for the photocatalytic isomerization synthesis of cis-olefin.

Key words: Cis-alkene, photocatalytic isomerization, photosensitizer

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Lin Ruhai, Mao Wei, Tu Donghuai, Dong Xingzong, Ma Hui, Lu Jian. Synthesis of cis-alkene with electron-withdrawing groups via photocatalytic isomerization[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202505010.

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光催化异构化合成含吸电子取代基顺式烯烃研究

Synthesis of cis-alkene with electron-withdrawing groups via photocatalytic isomerization

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