Chinese Journal of Organic Chemistry 2024, 44(7)

- About the Cover:
  
  N-Heterocyclic carbene (NHC) is a kind of important small organic molecule catalyst, which plays a key role in the field of organic catalysis. A series of important advances have been made in the study of the umpolung of aldehyde compounds catalyzed by NHC. NHC cata-lyzed the umpolung of aldehyde compounds is intro-duced by Zhao, Yan and Chen on page 2204.
- About the Cover:
  
  A transition-metal-free strategy for the synthesis of tetrasubstituted furans is reported by Meng, Guo and Wang on page 2274. Promoted by boron trifluoride di-ethyl etherate, the reaction of alkynyl sulfoxides with ynamides/ynol ethers proceeded via a cascade process including cross-coupling of the two reactants, [3,3]- sulfonium rearrangement, and 5-exo-dig heterocyclization, leading to tetrasubstituted furan products.
- About the Cover:
  
  Based on our previous total synthesis of complex natural product elansolid A, a simplified analog of elansolid A featured with a cyclohexyl-fused 19-memebered macro-lactone was proposed, and its asymmetric total synthesis based on a convergent strategy and key reactions exem-plified by desymmetric alcoholysis of anhydride, Pd- catalyzed Stille coupling, Suzuki-Miyaura coupling as well as Mukaiyama macrolactonization was finished by Yang, Wu and Wang on page 2350.
- About the Cover:
  
  A manganese-catalyzed ring-opening C—C bond fluorination of cyclobutanols is reported by Wang, Liu, Zan, Sun, Liu, Li, and Liu on page 2333. Under mild conditions, the reaction provides a straightforward access to γ-fluorinated ketones using 10 mol% Mn(OAc)₂ as catalyst and electro- philic fluorination reagent, which was generated in situ from HF·Et₃N and PhIO, as fluorine source.
2024, 44(7)

25 July 2024
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REVIEWS ARTICLES HIGHLIGHTS

REVIEWS

Transition Metal Catalyzed Carbocycle-Selective Asymmetric Hydrogenation of Aromatic Rings

Qian Chen, Zhaobin Han, Kuiling Ding

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2063-2076 DOI: 10.6023/cjoc202403017

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Palladium-Catalyzed Cyclization of 1,6-Enynes

Wenjuan Liu, Pinhong Chen

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2077-2091 DOI: 10.6023/cjoc202401032

Abstract( 322) HTML( 10) PDF(908KB)( 278 )

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Advances in the Synthesis of Organogermaniums Based on the Addition Reactions of Alkenes and Alkynes

Leiyang Lv, Yani Luo, Zhiping Li

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2092-2109 DOI: 10.6023/cjoc202401014

Abstract( 336) HTML( 11) PDF(949KB)( 445 )

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Developments in Visible Light Catalyzed Asymmetric Minisci Reactions

Wenya Li, Yu Wang, Jiangqi Chen, Dan Shi, Liang Zhang, Xiaochun Yu, Zheng-Jun Wang

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2110-2123 DOI: 10.6023/cjoc202312016

Abstract( 507) HTML( 16) PDF(1041KB)( 806 )

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Photoresponsive Dynamic Supramolecular Assembly and Regulation of Stiff-Stilbenes

Qianhong Cao, Yongmei Xiao, Guoxing Liu

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2124-2135 DOI: 10.6023/cjoc202312026

Abstract( 183) HTML( 5) PDF(3050KB)( 151 )

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Recent Advances of Minisci Reactions in Aqueous Solution

Wengui Wang, Shoufeng Wang

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2136-2146 DOI: 10.6023/cjoc202401015

Abstract( 244) HTML( 7) PDF(677KB)( 222 )

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Vinylene Carbonate: A Versatile Synthon in Organic Synthetic Chemistry

Yu Lin, Haifeng Fu, Hua Cao, Xiang Liu

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2147-2173 DOI: 10.6023/cjoc202401036

Abstract( 271) HTML( 6) PDF(1279KB)( 321 )

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Advances in the Synthesis of Mono/Di/Polyfluoroalkyl Ethers

Dongxue Song, Hongqiong Zhao, Ying Xu, Chenfeng Ji, Yingjie Liu

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2174-2203 DOI: 10.6023/cjoc202401003

Abstract( 216) HTML( 9) PDF(1522KB)( 304 )

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N-Heterocyclic Carbene Catalyzed the Umpolung of Aldehyde Compounds

Ming Zhao, Rui Yan, Hu Chen

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2204-2215 DOI: 10.6023/cjoc202401009

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ARTICLES

Metal-Free 1,8-Diazabicyclo(5.4.0)-undec-7-ene Mediated Synthesis of α-Acetal Amides through Reaction of Glyoxylic Acid Acetalde with Aryl Isothiocyanates

Rou Ding, Siyu Shi, Chao Ma, Wei Wei, Yufen Lü

Chinese Journal of Organic Chemistry 2024, 44 (7), pp 2216-2222 DOI: 10.6023/cjoc202403029

Abstract( 144) HTML( 10) PDF(583KB)( 140 )