Chinese Journal of Organic Chemistry ›› 2024, Vol. 44 ›› Issue (7): 2110-2123.DOI: 10.6023/cjoc202312016 Previous Articles     Next Articles

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可见光催化不对称Minisci反应研究进展

李文雅a, 王煜a, 陈江琦a, 史丹b, 张良a, 余小春a,*(), 王正军a,c,*()   

  1. a 温州大学化学与材料工程学院 浙江温州 325035
    b 温州市市场监督管理局 温州市质量技术检测科学研究院 浙江温州 325052
    c 湖南大学化学生物传感与计量学国家重点实验室 长沙 430100
  • 收稿日期:2023-12-16 修回日期:2024-02-12 发布日期:2024-03-28
  • 基金资助:
    湖南大学化学生物传感与计量学国家重点实验室开放项目(20230767); 温州市基础性科研(G20220020)

Developments in Visible Light Catalyzed Asymmetric Minisci Reactions

Wenya Lia, Yu Wanga, Jiangqi Chena, Dan Shib, Liang Zhanga, Xiaochun Yua(), Zheng-Jun Wanga,c()   

  1. a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035
    b Wenzhou Market Supervision Administration, Wenzhou Quality and Technical Testing Science Research Institute, Wenzhou, Zhejiang 325052
    c State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082
  • Received:2023-12-16 Revised:2024-02-12 Published:2024-03-28
  • Contact: E-mail: xiaochunyu@wzu.edu.cn;zj0608wang@163.com
  • Supported by:
    Open Project of State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University(20230767); Basic Scientific Research Projects in Wenzhou City(G20220020)

N-Heterocyclic aromatics are among the most prevalent motifs in natural products, pharmaceuticals, and organic materials. Therefore, the selective functionalization of N-heterocyclic aromatics, represented by the Minisci reaction, has always been a hot topic for chemists. Meanwhile, in recent years, photocatalysis has sparked a new research trend as a green, safe, clean, and renewable catalytic method. Although a review has been conducted on photoinduced Minisci reactions in recent years, the exploration of asymmetric Minisci reactions is limited. The research progress on visible-light photocatalytic asymmetric Minisci reactions in recent years from the classification of free radical precursors and different reaction pathways is summarized. Furthermore, prospects for future development are also discussed.

Key words: asymmetric Minisci reaction, photocatalysis, N-heterocyclic aromatics, free radicals