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化学学报
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化学学报 ›› 2002, Vol. 60 ›› Issue (3): 499-503. 上一篇    下一篇

研究论文

新型芳香胺－邻醌聚合物的合成及其作为纳料固定化酶载体的研究

郭刚军;马林;毛学圃;古练权;王骏   

  1. 中册大学化学与化学工程学院,广州(510275);香港吕文大学生物化学系.香港
  • 发布日期:2002-03-15

A Novel Arylamine-o-quinone Polymer: Synthesis and Application as a Nano-support for Immobilized Enzymes

Guo Gangjun;Ma lin;Mao Xuepu;Gu Lianquan;Wang Jun   

  1. Chemistry and Chemical Engineering School, Zhongshan University, Guanzhou(510275);Department of Biochemistry, The Chinese University of Hongkong.Hongkong
  • Published:2002-03-15

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561

被引次数

4

以碘酸盐为氧化剂，通过氧化－迈克尔加成反应，由邻苯二酚和4,4'-亚甲基 苯胺合成了一种新的功能聚合物，芳香胺－邻醌聚合物。这种聚合物表面由分布均 匀的纳料颗粒和孔穴构成。由于这种聚合物分子含有疏水骨架、羰基和胺基的有序 分布，以及独特的纳料微观颗粒和孔穴结构，使其成为吸附法固定化酶的良好载 体。

关键词: 芳香族胺, 加成反应, 苯二酚, 苯胺 P, 固定化酶, 醌, 吸附, 载体

Using sodium iodate as an oxidizing agent, a novel arylmaine-o- quinone polymer was synthesized from 1,2-dihydroxybenzene and 4,4'- methylene dianiline by an oxidation-Michael addition. The polymer surface was constructed by uniform nanoparticles and nanoholes (about 50 nm). Owing to its aromatic backbone, amino and carbonyl groups, and its characteristic in nano-size surface structure, the polymer can be used as an ideal support for immobilized enzymes by absorption.

Key words: AROMATIC AMINES, ADDITION REACTION, BENZENEDIOL, FIXED ENZYME, QUINONE, ADSORPTION, CARRIERS

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