化学学报 ›› 1987, Vol. 45 ›› Issue (6): 594-597. 上一篇    下一篇

研究论文

FOURIER自退卷积方法增加光谱分辨的一则应用--一些双环酮酸羰基红外光谱吸收的研究

聂崇实;张才华;吴毓林;马颖   

  1. 中国科学院上海有机化学研究所;中国石油化工总公司扬子公司烯烃厂
  • 发布日期:1987-06-15

An application of fourier self-deconvolution method for spectral band resolution enhancement--studies of the carbonyl IR absorptions for some bicyclic ketoacids

NIE CHONGSHI;ZHANG CAIHUA;WU YULIN;MA YING   

  • Published:1987-06-15

关键词: 抗疟药, 红外分光光度法, 双环, 平衡常数, 吸收谱, 青蒿素, 羰基, 酮酸, 酮 P, 分辨率

Fourier self-deconvolution method is properly used to resolve the overlapped keto and carboxylic IR absorption bands for some bicyclic keto acids, e.g. I and II. The bands are then able to be characterized. With some approximation, the equilibrium constant of the dimerization of bicyclic keto acids in nonpolar solvents at room temperature was calculated from sectral data.

Key words: ANTIMALARIALS, INFRARED SPECTROPHOTOMETRY, BICYCLIC, EQUILIBRIUM CONSTANT, ABSORPTION SPECTRA, ARTEANNUIN, CARBONYL GROUP, KETONE ACID, KETONE P, RESOLVING POWER

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