化学学报 ›› 1987, Vol. 45 ›› Issue (6): 602-605. 上一篇    下一篇

研究论文

昆虫信息素结构鉴定和合成的研究XXIV.淡色库蚊产卵引诱信息素(45R,6S)-6-乙酰氧基-5-十六酸内酯的合成

林国强;蒋产颖;郭广忠;夏克敏   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1987-06-15

Studies on the identification and syntheses fo insect pheromones XXIV. Synthesis of he mosquito oviposition attractant pheromone, (5R,6S)-6-acetoxy-5-hexadecanolide

LIN GUOQIANG;JIANG YANGYING;GUO GUANGZHONG;XIA KEMING   

  • Published:1987-06-15

关键词: 内酯, 十六碳化合物, 羧酸酯, 乙酰氧基, 昆虫激素, 性信息素, 光学异构, 库蚊属, 产卵

The oviposition attractant pheromone, I, of the mosquito Culex pipienes fatigans was prepared from (R)-(+)-glyceraldehyde acetonide via 11 steps in an overall yield of 15%.

Key words: LACTONES, C16 COMPOUNDS, CARBOXYLIC ACID ESTER, ACETOXY GROUP, INSECT HORMONE, SEX PHEROMONE, OPTICAL ISOMERISM, CULEX, SPAWNING

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