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化学学报
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化学学报 ›› 1990, Vol. 48 ›› Issue (4): 372-376. 上一篇    下一篇

研究论文

烯丙基卤和锡与醛, 酮反应合成高烯丙基醇

吴世晖;黄邦洲;朱天民;姚丹姝;初永亮   

  1. 复旦大学化学系
  • 发布日期:1990-04-15

Synthesis of homoallyl alcohol from carbonyl compounds by allyl halide and tin

WU SHIHUI;HUANG BANGZOU;ZHU TIANMIN;YAO DANSHU;CHU YONGLIANG   

  • Published:1990-04-15

PDF

611

被引次数

7 | 5

烯丙基溴或烯丙基碘和锡能以较高的产率与含有羟基、酚羟基、硝基、溴等活性基团的羰基化合物作用合成相应的高烯丙基醇, 文中讨论了不同卤素以及溶剂性质、水的含量对反应的影响。

关键词: 碘化合物, 溴化合物, 锡, 醇, 羰基化合物, 醛, 酮, 烯丙基, 烯丙基, 有机试剂

Homoallyl alcs. containing hydroxy, phenolic hydroxyl, aromatic nitro and bromo groups can be obtained directly from the reaction of corresponding carbonyl compounds with allyl halide and tin powder in good yields. The effect of solvents and the amount of water present on product yields were discussed.

Key words: IODINE COMPOUNDS, BROMINE COMPOUNDS, TIN, ALCOHOL, CARBONYL COMPOUNDS, ALDEHYDES, KETONE, ALLYL GROUP, ALLYL GROUP, ORGANIC REAGENTS

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