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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (2): 208-212. 上一篇    下一篇

研究论文

介孔固体超强酸催化剂的制备与结构表征

郭锡坤, 秦国平, 谌宁   

  1. 汕头大学化学系, 汕头, 515063
  • 投稿日期:2003-06-12 修回日期:2003-08-07 发布日期:2014-01-26
  • 通讯作者: 郭锡坤,E-mail:o_rsc@stu.edu.cn E-mail:o_rsc@stu.edu.cn
  • 基金资助:
    广东省教育厅自然科学研究项目(No.200064)、广东省科技计划项目(No.2003C33004)、汕头大学研究与发展基金(No.130-512042)资助项目.

Preparation and Structure Characterization of Mesoporous Solid Superacid Catalysts

GUO Xi-Kun, QIN Guo-Ping, SHEN Ning   

  1. Department of Chemistry, Shantou University, Shantou 515063
  • Received:2003-06-12 Revised:2003-08-07 Published:2014-01-26

PDF

393

被引次数

68

以累托土为基质,采用硅锆双组分交联剂和SO42-改性的方法,研制交联粘土介孔固体超强酸(SO42-/SiZrR),借助XRD, BET法,FT-IR, Hammett指示剂法,NH3-TPD, Py-IR和DTA等现代分析测试方法,表征其结构.实验结果表明:500℃焙烧后,SO42-/SiZrR的Hammett酸度函数Ho＜-11.93,最可几孔径分布在2.3 nm左右,具有超强酸性和介孔结构;其超强酸中心属于L酸中心,是主要的催化活性中心;硅锆双组分交联柱能使交联粘土的热稳定性提高,以累托土为基质的交联粘土比以蒙脱土为基质的交联粘土热稳定性高.

关键词: 累托土, 介孔固体超强酸, 催化剂, 结构表征

By utilizing rectorite as matrix, the mesoporous solid superacid in form of pillared clays (SO42-/SiZrR), pillared by Si-Zr bipillaring agent and modified subsequently by SO42-, was prepared. Its structure was characterized by means of XRD, BET, FT IR, Hammett indicator, NH3-TPD, Py-IR, DTA etc. The results show that after being calcined at 500℃, SO42-/SiZrR exhibited superacidity and mesoporous structure with the Hammett acidity function Ho-11.93 and the most probable pore size at ca. 2.3 nm. The superacid sites were attributed to Lewis acid sites and proved to be dominant active center. The Si-Zr bipillars can enhance the thermal stability of the resulting catalysts substantially. By utilizing rectorite as matrix, the thermal stability of pillared clay is, in particular, higher than that of pillared clay which utilizes montmorillonite as matrix.

Key words: rectorite, mesoporous solid superacid, catalyst, structure characterization