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化学学报
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化学学报 ›› 1997, Vol. 55 ›› Issue (6): 622-624. 上一篇    

研究论文

C~6~0O异构体的研究

郝策;吴师;滕启文;赵学庄;李文兰;唐敖庆;封继康   

  1. 南开大学化学系.天津(300071);南开大学吸附与分离功能高分子材料国家重点 实验室;吉林大学理论化学研究所.长春(130023)
  • 发布日期:1997-06-15

Spectroscopic study on the isomers of C~6~0O

Hao Ce;Wu Shi;Teng Qiwen;Zhao Xuezhuang;Li Wenlan;Tang Aoqing;Feng Jikang   

  1. Nankai Univ, Dept Chem.Tianjin(300071);Jilin Univ, Inst Theoret Chem. Changchun(130023)
  • Published:1997-06-15

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本文用臭氧氧化C~6~0的苯溶液,用HPLC分析产物,室温下氧化产物只得到一个C~6~0O异构体组分峰。低温下产物得到两个C~6~0O异构体组分峰。多出的一个峰经实验与理论的研究,表明它很可能是异构体C~6~0O(C~s)。

关键词: 异构体, C~6~0, 氧化产物, HPLC, 氧化, 臭氧

The reaction of C~6~0 with ozone in benzen results in the formation of C~6~0 oxides. Two isomers of C~6~0O were formed at 10℃, isolated and the UV-vis spectra of both isomers were obtained. The UV-vis spectrum of C~6~0O(I) is same as C~6~0O(C~2~v) and that of C~6~0O(II) is in similar to theoretical one of C~6~0O(C~s).

Key words: ISOMER, OXIDATION PRODUCTS, HPLC, OXIDATION, OZONE

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