Study of molecular complexation of acrylonitrile and aromatics

Abstract

By means of the same type of Rose-Drago equation, the 1:1 mol. complex equilibrium constants of acrylonitrile with some aromatic donors, namely, benzene, toluene, ethylbenzene, xylenes, mesitylenes and styrene have been measured by UV/Vis and NMR spectroscopic techniques. It has been found that the complex constants determine by these two methods are reasonablely in agreement.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, AROMATIC HYDROCARBON, CALCULATION, NMR SPECTROMETRY, ACRYLONITRILE, COMPLEXATION, COMPLEX CONSTANT, VAN DER WAALS' FORCES

CLC Number:

O621.16

Cite this article

ZHOU YANHUA;ZHENG GUOKANG. Study of molecular complexation of acrylonitrile and aromatics[J]. Acta Chimica Sinica, 1987, 45(4): 391-394.

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丙烯腈与芳烃分子配位作用的研究