Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (11): 1140-1144. Previous Articles     Next Articles

Original Articles

高分散的炭载Au纳米催化剂的制备、表征和催化活性

李品将,董守安*,唐春,杨生春,顾永万,李楷中   

  1. (昆明贵金属研究所 昆明 650221)
  • 投稿日期:2005-05-26 修回日期:2006-02-14 发布日期:2006-06-15
  • 通讯作者: 董守安

Preparation, Characterization and Catalytic Activity of Highly Dispersed Gold Nanoparticle Supported on Carbon Catalyst

LI Pin-Jiang, DONG Shou-An*, TANG Chun, YANG Sheng-Chun, GU Yong-Wan, LI Kai-Zhong   

  1. (Kunming Institute of Precious Metals, Kunming 650221)
  • Received:2005-05-26 Revised:2006-02-14 Published:2006-06-15
  • Contact: DONG Shou-An

The catalyst of highly dispersed gold nanoparticle supported on active carbon was prepared by sodium citrate reduction-colloid gold immobilization method, and its catalytic activity was evaluated by the liquid phase catalytic oxidation reaction of glucose to gluconic acid. The research results show that the sodium citrate amounts have important influence on the size of gold particles in gold colloidal preparation and the catalytic activity of Au/C catalyst obtained. The decrease of the activity for repeatedly used Au/C catalyst may be attributed to the decrease of the Auδ+-Oδ- binding state on the catalyst surface. At the same time the catalytic activity for the liquid phase oxidation of glucose was compared between the prepared Au/C catalyst and the commercial Pd/C catalyst, and the results indicated that the Au/C catalyst was advantageous over Pd/C catalyst.

Key words: Au/C catalyst, preparation, characterization, catalytic activity, glucose