Synthesis and crystallographic structure of substituted dodecacarbonyltriruthenium by heptene hydride cluster H~3Ru~3(CO)~9(C~7 H~1~1)

Acta Chimica Sinica ›› 1994, Vol. 52 ›› Issue (2): 160-165. Previous Articles Next Articles

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庚烯配位的羰基钌氢簇合物H~3Ru~3(CO)~9(C~7H~1~1)的合成及晶体结构

梁丽君;罗玉忠;郁开北

中国科学院兰州化学物理研究所;中国科学院成都分析测试中心

发布日期:1994-02-15

Synthesis and crystallographic structure of substituted dodecacarbonyltriruthenium by heptene hydride cluster H~3Ru~3(CO)~9(C~7 H~1~1)

LIANG LIJUN;LUO YUZHONG;YU KAIBEI

Published:1994-02-15

Abstract

Substitution of Ru3(CO)12 by heptene gave H3Ru3(CO)9(C7H11). The structure of the product is speculated by the anal. of IR, 1H NMR, 13C NMR, MS and elementary anal. The double bond in heptene was opened. An x-ray diffraction of the product has unequivocally established its structure. The cluster is triclinic space, and the space group is P1. a 0.9726(2) nm, b 0.9868(1) nm, c 1.1104(2) nm, a 103.22(1), b 89.91(1), g - 91.55(1)? Z = 2, m = 21.59 cm-1, dc = 2.09 g/cm3, F (000) = 628, R = 0.0371.

Key words: CRYSTAL STRUCTURE, CARBONYL COMPLEX, CLUSTER COMPOUND, HEPTENE P, RUTHENIUM COMPLEX

CLC Number:

O611.662

Cite this article

LIANG LIJUN;LUO YUZHONG;YU KAIBEI. Synthesis and crystallographic structure of substituted dodecacarbonyltriruthenium by heptene hydride cluster H~3Ru~3(CO)~9(C~7 H~1~1)[J]. Acta Chimica Sinica, 1994, 52(2): 160-165.

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庚烯配位的羰基钌氢簇合物H~3Ru~3(CO)~9(C~7H~1~1)的合成及晶体结构

Synthesis and crystallographic structure of substituted dodecacarbonyltriruthenium by heptene hydride cluster H~3Ru~3(CO)~9(C~7 H~1~1)

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