Synthesis of N,N-dimethylformamide-meso-tetra(sodium-p-sulfonatophenyl)porphyrinatorhodium (II) and photoassisted reduction of water to hydrogen

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (10): 1024-1026. Previous Articles Next Articles

Original Articles

Rh(DMF)TPPS.5H2O的合成及光助还原水放氢的研究

贾殿赠;安兴民

新疆大学化学系

发布日期:1988-10-15

Synthesis of N,N-dimethylformamide-meso-tetra(sodium-p-sulfonatophenyl)porphyrinatorhodium (II) and photoassisted reduction of water to hydrogen

JIA DIANZENG;AN XINGMIN

Published:1988-10-15

Abstract

Rh(DMF)TPPS.5H2O [TPPSH2 = meso-tetra(sodium p-sulfonatophenyl)porphyrin] was prepared and characterized by elemental anal., IR, 1H NMR, ESR and TGA. The coordination geometry and valence state of the formed complex are discussed. The photoredn. of water by homogeneous 3-component system consisting of Rh(DMF)TPPS.5H2O, TiCl3 and K2PtCl6 was studied.

Key words: PORPHINE P, INFRARED SPECTROPHOTOMETRY, WATER, CHLORIDE, ELEMENTAL ANALYSIS, HYDROGEN, PROTON MAGNETIC RESONANCE SPECTROMETRY, DMF, POTASSIUM CHLORIDE, THERMOGRAVIMETRY

CLC Number:

O644

Cite this article

JIA DIANZENG;AN XINGMIN. Synthesis of N,N-dimethylformamide-meso-tetra(sodium-p-sulfonatophenyl)porphyrinatorhodium (II) and photoassisted reduction of water to hydrogen[J]. Acta Chimica Sinica, 1988, 46(10): 1024-1026.

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Rh(DMF)TPPS.5H2O的合成及光助还原水放氢的研究

Synthesis of N,N-dimethylformamide-meso-tetra(sodium-p-sulfonatophenyl)porphyrinatorhodium (II) and photoassisted reduction of water to hydrogen

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