Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (3): 301-304. Previous Articles     Next Articles

Original Articles

氟烷基化和氟烷氧基化的研究 22: 四醋酸铅催化氟烷基碘对烯烃的加成

陈庆云;陈建国   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1988-03-15

Studies on fluoroalkylation and fluoroalkoxylation 22: Lead tetraacetate induced fluoroalkylation of olefins with fluoroalkyl iodides

CHEN QINGYUN;CHEN JIANGUO   

  • Published:1988-03-15

The addition reaction of fluoroalkyl iodides to olefins could be catalyzed by Pb(OAc)4 to give the corresponding adducts. The reaction was also induced by PbO2. When diallyl ether was used as a substrate, the formation of THF derivatives in both cases indicated the involvement of free radical intermediates.

Key words: IODINE COMPOUNDS, CATALYST, ALKENE, LEAD COMPOUNDS, FLUOROHYDROCARBON, ADDITION REACTION, ACETIC ACID P, NSFC

CLC Number: