Preparation and Luminescent Properties of Series of Strontium Metaborate Light-emitting Materials

doi:10.6023/A1108224

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (03): 247-253.DOI: 10.6023/A1108224 Previous Articles Next Articles

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偏硼酸锶系列发光材料的制备及其发光性能研究

黄宏升, 刘志宏

陕西省大分子科学重点实验室陕西师范大学化学化工学院西安 710062

投稿日期:2011-08-22 修回日期:2011-11-12 发布日期:2011-11-21
通讯作者: 刘志宏 E-mail:liuzh@snnu.edu.cn
基金资助:
国家自然科学基金(No. 20871078)和陕西省自然科学研究计划(No. SJ08B01)资助项目.

Preparation and Luminescent Properties of Series of Strontium Metaborate Light-emitting Materials

Huang Hongsheng, Liu Zhihong

Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710062

Received:2011-08-22 Revised:2011-11-12 Published:2011-11-21
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20871078), and the Natural Science Foundation of Shaanxi Province of China(No. SJ08B01).

The SrB₂O₄·4H₂O and SrB₂O₄·4H₂O:Eu³⁺ light-emitting materials have been synthesized by liquid coprecipitation method, and SrB₂O₄ and SrB₂O₄:Eu³⁺ have been synthesized by calcination precursor method. All the as-prepared products were characterized by the XRD, EDS and SEM, respectively. Their luminescent properties were investigated by fluorescence spectroscopy, and the influences of reaction time and the doping concentration of Eu³⁺ on the emission intensities have also been investigated. The results show that the matrixes of SrB₂O₄·4H₂O and SrB₂O₄ have stronger luminescence in the UV region, and SrB₂O₄·4H₂O:Eu³⁺ and SrB₂O₄:Eu³⁺ samples have the strongest emission peaks near 613 nm. By adjusting the reaction time and increasing the amount of doping, the quenching effect of structural water on the luminescence can be overcome, which improves the luminescence of SrB₂O₄·4H₂O:Eu³⁺ with higher redorange ratio. It shows that SrB₂O₄·4H₂O is a new good hydrated borate matrix for light-emitting materials.

Key words: strontium metaborate, hydrated borate, preparation, luminescent property

Cite this article

Huang Hongsheng, Liu Zhihong. Preparation and Luminescent Properties of Series of Strontium Metaborate Light-emitting Materials[J]. Acta Chimica Sinica, 2012, 70(03): 247-253.

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偏硼酸锶系列发光材料的制备及其发光性能研究

Preparation and Luminescent Properties of Series of Strontium Metaborate Light-emitting Materials

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