有机化学 ›› 2012, Vol. 32 ›› Issue (02): 397-399 .DOI: 10.6023/cjoc1104085 上一篇    下一篇

研究简报

含有螺环己烷结构的稠环斯德酮的合成

张站斌, 张红海   

  1. 北京师范大学化学学院 北京 100875
  • 收稿日期:2011-04-08 修回日期:2011-09-19 发布日期:2012-03-09
  • 通讯作者: 张站斌 E-mail:zhangzb@bnu.edu.cn

Synthesis of Fused-Ring Sydnones with a Spirocyclohexane Moiety

Zhang Zhanbin, Zhang Honghai   

  1. College of Chemistry, Beijng Normal University, Beijing 100875
  • Received:2011-04-08 Revised:2011-09-19 Published:2012-03-09

3-(3-芳基-3-羟基丙基)斯德酮在三氟化硼乙醚的催化作用下可以与环己酮发生类似于Oxa-Pictet-Spengler 反应的成环反应, 生成带有螺环己烷结构的稠环斯德酮.

关键词: 斯德酮, 环己酮, 螺环化合物, 合成

Fused-ring sydnones with a spiro cyclohexane moiety were prepared via oxa-Pictet-Spengler reaction of 3-(3-aryl-3-hydroxypropyl)sydnones with cyclohexanone in the presence of boron trifluoride ether complex.

Key words: sydnone, cyclohexanone, spiro compound, synthesis