多硝基氮杂稠环化合物合成及性能

doi:10.6023/cjoc201512024

摘要/Abstract

氮杂稠环是构建含能化合物的重要结构单元, 硝胺基(NNO₂)是赋予氮杂稠环能量的主要源泉. 目前, 多硝基氮杂稠环化合物是含能化合物领域的重要研究方向之一. 全面介绍了多硝基氮杂双环、氮杂(三元以上)稠环以及氮杂螺桨烷等氮杂稠环类含能化合物母体骨架的构建与N-硝化方法, 同时概述了相关含能化合物的主要物化、爆轰性能. 重点综述了五硝基五氮杂[3.3.3]螺桨烷、六硝基六氮杂[3.3.3]螺桨烷母环骨架的构建策略以及针对此类空间高度拥挤、稳定性较差的骨架所进行的N-硝化探索研究.

关键词: 含能化合物, 氮杂稠环, 合成, N-硝化, 性能

Fused aza-polycyclic structures play an important role in the synthesis of energetic compounds and the presence of NNO₂ groups renders them a rich source of energy. Currently, fused aza-polynitrocyclic compounds have gained considerable prominence as novel energetic compounds. This review focuses on the synthesis of various ring skeletons of the aza-bicyclic, aza-polycyclic and aza-propellane-derivatized energetic compounds as well as the studies of N-nitration, physicochemistry and detonation properties. The synthesis of pentaaza[3.3.3]propellane and hexaaza[3.3.3]propellane is highlighted and N-nitration explorations of these high-strained unstable skeletons are discussed in details.

Key words: energetic compounds, fused aza-polycyclic structure, synthesis, N-nitration, properties

引用此文

张俊林, 肖川, 翟连杰, 王锡杰, 毕福强, 王伯周. 多硝基氮杂稠环化合物合成及性能[J]. 有机化学, 2016, 36(6): 1197-1207.

Zhang Junlin, Xiao Chuan, Zhai Lianjie, Wang Xijie, Bi Fuqiang, Wang Bozhou. Synthesis and Properties of the Fused Aza-polynitrocyclic Compounds[J]. Chin. J. Org. Chem., 2016, 36(6): 1197-1207.

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