有机化学 ›› 2018, Vol. 38 ›› Issue (1): 62-74.DOI: 10.6023/cjoc201708023 上一篇    下一篇

所属专题: 热点论文合辑 元素有机化学合辑2018-2019 有机光催化合辑

综述与进展

磷自由基对不饱和键的双官能化反应的研究进展

高玉珍a,b, 唐果a, 赵玉芬a   

  1. a 厦门大学化学化工学院 福建省化学生物学重点实验室 厦门 361005;
    b 中国科学院福建物质结构研究所 煤制乙二醇及相关技术重点实验室 福州 350002
  • 收稿日期:2017-08-11 修回日期:2017-08-31 发布日期:2017-09-08
  • 通讯作者: 赵玉芬 E-mail:yfzhao@xmu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21232005,21375113)、重点基础研究发展计划(No.2013CB910700)、中央高校基本科研业务费(No.20720160030)、博士后创新人才支持计划(No.BX201700244)资助项目.

Recent Advances of Phosphorus-Centered Radical Promoted Difunctionalization of Unsaturated Carbon-Carbon Bonds

Gao Yuzhena,b, Tang Guoa, Zhao Yufena   

  1. a Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005;
    b Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002
  • Received:2017-08-11 Revised:2017-08-31 Published:2017-09-08
  • Contact: 10.6023/cjoc201708023 E-mail:yfzhao@xmu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21232005, 21375113), the National Basic Research Program of China (No. 2013CB910700), the Fundamental Research Funds for the Central Universities (No. 20720160030), the National Postdoctoral Program for Innovative Talents (No. BX201700244).

有机膦化合物在有机反应、光电材料、阻燃材料以及药物化学等研究领域都具有广泛的用途,因而探索更高效、更绿色的方法实现有机膦化合物的合成是有机膦化学工作者的主要目标之一.通过磷自由基与不饱和化合物的双官能团化反应可以在一步反应中实现含磷杂环以及多环化合物的构建.按磷自由基引发方式的不同,对近年来磷自由基与不饱和化合物的双官能团化反应的研究进展进行了综述.

关键词: 磷自由基, 双官能团化, 不饱和化合物

The scientists have been working on developing more efficient and green ways to synthesize organophosphorus compounds as they have broad utilities such as reagents for chemical reactions, photovoltaic materials, flame retardants, biologically active molecules and so on. The difunctionalization reactions between P-center radicals and unsaturated compounds provide powerful methods for the synthesis of organophosphorus compounds in least and concise steps. This review will summarize the recent development in this area on the basis of different types of P-centered radical initiators.

Key words: phosphorus-centered radical, difunctionalization, unsaturated compounds