有机化学 ›› 2018, Vol. 38 ›› Issue (5): 1207-1213.DOI: 10.6023/cjoc201711036 上一篇    下一篇

研究论文

以芳基亚磺酸钠为硫源合成炔硫醚和不对称二硫醚化合物

林雅玫, 易文斌   

  1. 南京理工大学化工学院 南京 210094
  • 收稿日期:2017-11-21 修回日期:2017-12-17 发布日期:2018-01-10
  • 通讯作者: 易文斌,E-mail:yiwb@njust.edu.cn E-mail:yiwb@njust.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21776138,21476116)、中央大学基础研究基金(No.30916011102)及江苏省青蓝计划和六大高峰人才资助项目.

A Route to Alkynyl Sulfides and Asymmetric Disulfides from Sodium Arylsulfiniate

Lin Yamei, Yi Wenbin   

  1. Chemical Engineering College, Nanjing University of Science & Technology, Nanjing 210094
  • Received:2017-11-21 Revised:2017-12-17 Published:2018-01-10
  • Contact: 10.6023/cjoc201711036 E-mail:yiwb@njust.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21776138, 21476116), the Fundamental Research Funds for the Central Universities (No. 30916011102) and the Qing Lan and Six Talent Peaks in Jiangsu Province.

在水相碘/三苯基膦体系中,以无嗅、易操作的芳基亚磺酸钠为硫源,合成了炔硫醚和不对称硫醚化合物.该法相比于其他文献的方法,具有操作简单、无过渡金属参与、无需使用有机溶剂和产率高等优点.

关键词: 水相反应, 芳基亚磺酸钠, 炔硫醚, 不对称二硫醚

A new approach for the synthesis of alkynyl sulfides and asymmetric disulfides with odorless, easy-to-handle sodium arylsulfiniates as the sulfur source in I2/PPh3 aqueous system has been developed. Compared with reported approaches, this protocol provides several merits including simple procedures, free of transition-metal catalysts and organic solvent, and high yields.

Key words: reaction in water, sodium arylsulfiniate, alkynyl sulfide, asymmetric disulfide