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有机化学 ›› 2005, Vol. 25 ›› Issue (12): 1560-1564. 上一篇    下一篇

研究论文

3-对甲氧基苯基-和3-对羟基苯基-1-氨基-3a,4,5,9b-四氢化-9b-羟基-3H-环戊烯并[a]萘-2-甲腈的合成和晶体结构

史达清*，荣良策，王菊仙，庄启亚   

  1. (徐州师范大学化学系 徐州 221116)
  • 收稿日期:2005-01-05 修回日期:2005-06-22 发布日期:2005-11-30
  • 通讯作者: 史达清

Synthesis and Crystal Structure of 3-(4'-Methoxyphenyl)- and 3-(4'-Hydroxyphenyl)-1-amino-3a,4,5,9b-tetrahydro-9b-hy-droxy-3H-cyclopenta[a]naphthalene-2-carbonitrile

SHI Da-Qing*, RONG Liang-Ce, WANG Ju-Xian, ZHUANG Qi-Ya   

  1. (Department of Chemistry, Xuzhou Normal University, Xuzhou 221116)
  • Received:2005-01-05 Revised:2005-06-22 Published:2005-11-30
  • Contact: SHI Da-Qing

PDF

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用低价钛试剂(TiCl4-Zn)与2-氰基-3-对甲氧基苯基-3-(1-四氢萘酮-2-基)丙腈反应合成了3-对甲氧基苯基-1-氨 基-3a,4,5,9b-四氢化-9b-羟基-3H-环戊烯并[a]萘-2-甲腈和3-对羟基苯基-1-氨基-3a,4,5,9b-四氢化-9b-羟基-3H-环戊烯并[a]萘-2-甲腈, 并用X射线衍射分析确定了这两个产物的结构.

关键词: 低价钛, 环戊烯并[a]萘-2-甲腈, 合成, 晶体结构

-(4'-Methoxyphenyl)- and 3-(4'-hydroxyphenyl)-1-amino-3a,4,5,9b-tetrahydro-9b-hy-droxy-3H- cyclopenta[a]naphthalene-2-carbonitriles were synthesized by the reaction of low-valent titanium reagent (TiCl4-Zn) with 2-cyano-3-(4'-methoxyphenyl)-3-(1-tetralon-2-yl)propionitrile. Their structures were determined by X-ray analysis.

Key words: synthesis, crystal structure, cyclopenta[a]naphthalene-2-carbonitrile, low-valent titanium reagent