有机化学 ›› 2011, Vol. 31 ›› Issue (02): 197-202. 上一篇    下一篇

研究论文

含脱氢松香骨架的1,8-萘酰亚胺衍生物的合成及其对阴离子的识别

张业1,2,冯少波1,潘英明1,义祥辉2,王恒山*,1   

  1. (1广西师范大学化学化工学院 桂林 541004)
    (2桂林师范高等专科学校化学与工程技术系 桂林 541001)
  • 收稿日期:2010-04-07 修回日期:2010-08-20 发布日期:2010-09-09
  • 通讯作者: 王恒山 E-mail:wang_hengshan@yahoo.com.cn;whengshan@yahoo.com
  • 基金资助:

    国家自然科学基金;广西教育厅科研项目资助项目;广西教育厅科研项目资助项目;广西教育厅科研项目资助项目;广西教育厅科研项目资助项目

Synthesis of Some Novel 1,8-Naphthalimides Bearing Dehydroabietyl Rosin Skeleton and Their Anion Recognition

Zhang Ye1,2 Feng Shaobo1 Pan Ying-ming1 Yi Xianghui2 Wang Hengshan*,1   

  1. (1 College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004)
    (2 Department of Chemistry and Engineering Technology, Guilin Normal Col-lege, Guilin 541001)
  • Received:2010-04-07 Revised:2010-08-20 Published:2010-09-09

以歧化松香胺为原料合成了6个新型含脱氢松香骨架的1,8-萘酰亚胺衍生物2a2b3a3d, 其结构用1H NMR, 13C NMR, MS和元素分析进行了表征. 对3a3d进行了阴离子识别研究, 并对其识别机理进行了讨论.

关键词: 1,8-萘酰亚胺, 脱氢松香, 合成, 结构表征, 阴离子识别

Some novel 1,8-naphthalimide derivatives bearing dehydroabietyl rosin skeleton were synthesized from dehydroabietylamine. The title compounds were characterized by 1H NMR, 13C NMR, MS techniques and elemental analysis. The abilities of anion recognition by these 1,8-naphthalimide derivatives had been investigated. Then the mechanism of anion recognition of such 1,8-naphthalimides was discussed.

Key words: 1,8-naphthalimide, dehydroabietyl rosin, synthesis, characterization, recognition of anion