有机化学 ›› 2009, Vol. 29 ›› Issue (05): 788-793. 上一篇    下一篇

研究简报

离子液体中5,5-二甲基-1,3-环己二酮与N-芳亚甲基芳胺反应合成 吖啶衍生物

史达清*,a,b; 倪赛男b; 窦国兰b   


  1. (a苏州大学化学化工学院 江苏省有机合成重点实验室 苏州 215123)
    (b徐州师范大学化学化工学院 徐州 221116)
  • 收稿日期:2008-01-09 修回日期:2008-06-11 发布日期:2009-05-20
  • 通讯作者: 史达清

Synthesis of Acridine Derivatives Using the Reaction of 5,5-Dimethylcyclohexane-1,3-dione and N-Benzylideneaniline in Ionic Liquid

Shi, Daqing*,a,b; Ni, Sainan b; Dou, Guolanb   

  1. (a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering,
    Suzhou University, Suzhou 215123)
    (b College of Chemistry and Chemical Engineering, Xuzhou Normal University, Xuzhou 221116)
  • Received:2008-01-09 Revised:2008-06-11 Published:2009-05-20
  • Contact: Shi, Daqing

在离子液体[bmim]Br中, 5,5-二甲基-1,3-环己二酮与N-芳亚甲基芳胺反应合成了一系列四氢吖啶-1,8-二酮衍生物, 该反应具有适应性广、产率高、污染少、环境友好等优点.

关键词: 四氢吖啶-1,8-二酮, 离子液体, 5,5-二甲基-1,3-环己二酮, N-芳亚甲基芳胺

A series of tetrahydroacridine-1,8-dione derivatives were synthesized by the reaction of 5,5-dimethylcyclohexane-1,3-dione and N-benzylideneaniline in ionic liquid [bmim]Br. The reaction has the advantages of good yields, less pollution, simple operation and environmental friendliness.

Key words: ionic liquid, tetrahydroacridine-1,8-dione, 5,5-dimethylcyclohexane-1,3-dione, N-benzylidene- anili