有机化学 ›› 2011, Vol. 31 ›› Issue (05): 603-615. 上一篇    下一篇

综述与进展

含富勒烯结构单元酞菁的研究概况

李莹莹1,2,张改1,赵建社*,1   

  1. (1西北大学合成与天然功能分子化学教育部重点实验室 陕西省物理无机化学重点实验室
    西北大学化学与材料科学学院 西安 710069)
    (2陇东学院化学化工学院 庆阳 745000)
  • 收稿日期:2010-05-07 修回日期:2010-07-27 发布日期:2010-11-02
  • 通讯作者: 李莹莹 E-mail:liyingyinghx@163.com
  • 基金资助:

    环境友好型酞菁脱硫催化剂的研制

A Survey of Studies on Phthalocyanines Containing Fullerene Units

Li Yingying1,2 Zhang Gai1 Zhao Jian-she*,1   

  1. (1 Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Material Science, Northwest University, Xian 710069)
    (2 College of Chemistry & Chemical Engi-neering, Longdong University, Qingyang 745000)
  • Received:2010-05-07 Revised:2010-07-27 Published:2010-11-02
  • Contact: 莹莹 李 E-mail:liyingyinghx@163.com

通过不同的合成方法, 将富勒烯嫁接到酞菁环的周边或轴向位置上, 可以形成一类新型的具有特殊结构和性质的酞菁-富勒烯化合物. 综述了具有代表性的含富勒烯结构单元的酞菁的合成及电化学、光致电子转移、分子聚集和自组装等方面的研究概况.

关键词: 富勒烯, 酞菁, 合成, 性质

A new type of phthalocyanine-fullerene compounds, which have special structure and properties, can be obtained through attaching fullerene to the periphery or axial position of phthalocyanine by different synthetic methods. The synthetic approache, photo-induced electron transfer, electrochemical and aggrega-tion properties of phthalocyanine containing fullerene (C60) units are outlined.

Key words: fullerene, phthalocyanine, synthesis, property