有机化学 ›› 2011, Vol. 31 ›› Issue (09): 1395-1405. 上一篇    下一篇

综述与进展

硅杂环戊二烯的合成及应用研究进展

马庆宇*,1,关瑞芳1,李国忠1,冯圣玉2   

  1. (1济南大学材料科学与工程学院 济南 250022)
    (2山东大学化学与化工学院 济南 250100)
  • 收稿日期:2011-01-09 修回日期:2011-04-10 出版日期:2011-09-25 发布日期:2011-04-20
  • 通讯作者: 马庆宇 E-mail:mse_maqy@ujn.edu.cn

Progress in the Synthesis and Applications of Silole Compounds

Ma Qingyu*,1 Guan Ruifang1 Li Guozhong1 Feng Shengyu2   

  1. (1 School of Material Science and Engineering, University of Jinan, Jinan 250022)
    (2 School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100)
  • Received:2011-01-09 Revised:2011-04-10 Online:2011-09-25 Published:2011-04-20

硅杂环戊二烯是一种含硅的五元环, 是环戊二烯的类似物, 由于其具有特殊的电子结构, 在许多方面有广泛的应用. 综述了硅杂环戊二烯化合物的合成方法, 作为光电材料、化学传感器及生物传感器等方面的应用研究进展. 最后, 对硅杂环戊二烯的研究方向提出了展望.

关键词: 硅杂环戊二烯, 聚集诱导发光, 光电材料, 化学传感器, 生物传感器

Siloles are a group of silicon-containing five-membered cyclic dienes. Due to their unique electronic structures, they have been attracted much attention and potentially applied in many fields. In this review, we summarized recent progress in the synthesis of silole compounds and their applications as electroluminescent devices (EL), chemsensors, biosensors etc. Opposite to common phenomenon of aggregation-caused quenching (ACQ) of light emission in many luminophoric molecules, silole compounds exhibit aggregation-induced emission (AIE). Enlightened by this abnormal phenomenon, the applications of silole compounds are extremely extended, including traditional EL materials, chem-, bio-sensors and many fields in progress. At last, the future research of this research field is also prospected.

Key words: silole, aggregation-induced emission, electroluminescent devices, chemsensors, biosensor