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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (10): 1643-1647. 上一篇    下一篇

研究论文

1,1-二(2,4,6-三硝基苯甲酰胺基)-2,2-二硝基乙烯的合成

何佳1，金波*,1,2，彭汝芳*,1，楚士晋1，董海山2,3   

  1. (1西南科技大学材料科学与工程学院 四川省非金属复合与功能材料重点实验室-
    省部共建国家重点实验室培育基地 绵阳 621010)
    (2北京理工大学化工与环境学院 北京100081)
    (3中国工程物理研究院化工材料研究所 绵阳 621900)
  • 收稿日期:2011-01-03 修回日期:2011-05-03 发布日期:2011-06-01
  • 通讯作者: 金波 E-mail:6070831@163.com

Synthesis of 1,1-Dinitro-2,2-di(2,4,6-trinitrobenzoyl amino)ethylene

He Jia1 Jin Bo*,1,2 Peng Rufang*,1 Chu Shijin1 Dong Haishan2,3   

  1. (1 State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, School of Materials Science and Engineering Southwest University of Science and Technology, Mianyang 621010)
    (2 School of Chemical Engineering and Environment, Beijing Institute of Technol-ogy, Beijing 100081)
    (3 Institute of Chemical Materials, Chinese Academy of Engi-neering Physics, Chinese Academy of Sciences, Mianyang 621900)
  • Received:2011-01-03 Revised:2011-05-03 Published:2011-06-01

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被引次数

3

以1,1-二氨基-2,2-二硝基乙烯(FOX-7)和2,4,6-三硝基苯甲酰氯(TNBC)为原料反应合成得到了1,1-二(2,4,6-三硝基苯甲酰胺基)-2,2-二硝基乙烯, 并通过单因素试验和正交试验方法, 分别探讨了反应介质、缚酸剂、反应温度和反应时间等对产物产率的影响, 得到适宜的工艺条件为: FOX-7与TNBC物质的量的比1∶2.4, 以四氢呋喃(THF)为反应介质, N,N-二甲基甲酰胺(DMF)为缚酸剂, 反应温度0 ℃, 反应时间48 h, 产率可达94%. 采用紫外可见光谱(UV-Vis)、核磁共振氢谱(1H NMR)、核磁共振碳谱(13C NMR)、红外光谱(FT-IR)、质谱(MS)及元素分析等对产物的结构进行了表征. 利用差热分析仪对产物热稳定性进行了研究, 结果表明, 产物在空气中分解峰值温度为167 ℃, 理论计算爆速为7.434 km•s－1, 爆压为23.67 GPa.

关键词: 1,1-二氨基-2,2-二硝基乙烯(FOX-7), 2,4,6-三硝基苯甲酰氯(TNBC), 合成工艺, 热稳定性, 含能材料

A new explosive 1,1-dinitro-2,2-di(2,4,6-trinitrobenzoyl amino)ethylene 3 was synthesized by the reaction of 1,1-diamino-2,2-dinitroethylene (FOX-7) with 2,4,6-trinitrobenzoyl chloride (TNBC). The product was characterized by UV-Vis, 1H NMR, 13C NMR, FT-IR and MS techniques. The reaction conditions affecting the yields of product were investigated, and the optimum reaction conditions with 94% yield are 1∶2.4 molar ratio of FOX-7 and TNBC, reaction temperature 0 ℃ and reaction time 48 h. The thermal stability of product 3 was studied by differential thermal analysis (DTA). DTA curve showed that the peak temperature of decomposition was 167 ℃ in the atmosphere. The theoretical detonation velocity is 7.434 km•s－1, and the theoretical detonation pressure is 23.67 GPa.

Key words: 1,1-diamino-2,2-dinitroethylene (FOX-7), 2,4,6-trinitrobenzoyl chloride (TNBC), synthetic technology, thermal stability, energetic material

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