有机化学 ›› 2021, Vol. 41 ›› Issue (4): 1466-1488.DOI: 10.6023/cjoc202009019 上一篇    下一篇

综述与进展

吡唑含能离子盐的合成研究进展

李光磊a,b, 黄海丰b,c,*(), 杨军b,*(), 段红珍a,*()   

  1. a 中北大学理学院 太原 030051
    b 中国科学院上海有机化学研究所 中国科学院能量调控材料重点实验室 上海 200032
    c 中国科学院绿色过程制造创新研究院 北京 100190
  • 收稿日期:2020-09-08 修回日期:2020-09-28 发布日期:2020-11-04
  • 通讯作者: 黄海丰, 杨军, 段红珍
  • 基金资助:
    中国科学院绿色过程制造创新研究院自主部署联合基金(IAGM2020C06)

Progress in the Synthesis of Energetic Salts Based on Pyrazole

Guanglei Lia,b, Haifeng Huangb,c,*(), Jun Yangb,*(), Hongzhen Duana,*()   

  1. a School of Science, North University of China, Taiyuan 030051
    b Key Laboratory of Energy Regulation Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
    c Innovation Academy for Green Manufacture, Chinese Academy of Sciences, Beijing 100190
  • Received:2020-09-08 Revised:2020-09-28 Published:2020-11-04
  • Contact: Haifeng Huang, Jun Yang, Hongzhen Duan
  • About author:
    * Corresponding authors. E-mail: ;
  • Supported by:
    Innovation Academy for Green Manufacture, Chinese Academy of Sciences(IAGM2020C06)

吡唑环上有三个可修饰的碳位点和一个可修饰的NH位点, 通过对这四个位点的修饰(主要是引入硝基、硝胺基、氨基、羟基以及形成稠环等), 可设计出种类丰富的吡唑含能化合物. 同时, 相对于2,4,6-三硝基甲苯(TNT)、黑索金(RDX)、奥克托今(HMX)等常规含能化合物, 吡唑含能化合物具有氮含量高、生成焓高及感度低等优势. 近年来, 国内外基于吡唑骨架设计并合成了大量吡唑含能离子盐, 其中很多种化合物表现出高能及钝感等特性. 按单环吡唑含能离子盐、联环吡唑含能离子盐及稠环吡唑含能离子盐, 分类综述了近年来所报道的吡唑含能离子盐的合成及性能, 并对该类化合物的应用前景进行了展望.

关键词: 含能材料, 含能离子盐, 吡唑, 硝胺

The pyrazole ring has three modifiable carbon sites and one modifiable NH site. Based on the pyrazole ring, a variety of pyrazole energetic compounds can be designed by the introduction of nitro, nitramino, amino and hydroxyl group and the formation of fused rings. At the same time, compared with conventional energetic compounds such as 2,4,6-trinitro- benzene (TNT), hexahydro-1,3,5-trinitro-triazine (RDX) and 1,3,5,7-tetranitro-1,3,5,7-tetrazocane (HMX), energetic pyrazoles have the advantages of high nitrogen content, high enthalpy of formation and low sensitivities. In recent years, a large number of energetic salts based on pyrazole have been designed and synthesized around the world, including monocyclic energetic salts, bicyclic energetic salts and fused energetic salts based on pyrazole. Many of them exhibit the characteristics of high energy and low sensitivity. The synthesis and properties of recently reported energetic salts based on pyrazole are reviewed, and their applications in the field of energetic materials are prospected.

Key words: energetic material, energetic salt, pyrazole, nitramino