有机化学 ›› 2013, Vol. 33 ›› Issue (11): 2325-2333.DOI: 10.6023/cjoc201303053 上一篇    下一篇

综述与进展

还原型Heck反应的研究进展

杨晓梅a, 马莎a, 杜艳妮b, 陶云海b   

  1. a 云南中医学院 昆明 650500;
    b 云南大学化学科学与工程学院 昆明 650091
  • 收稿日期:2013-03-31 修回日期:2013-05-20 出版日期:2013-11-25 发布日期:2013-06-04
  • 通讯作者: 陶云海 E-mail:cloudsea2000@163.com
  • 基金资助:

    云南大学理(工)科校级科研(No. 2011YB12)及云南省教育厅基金(No. 2011Y112)资助项目.

Progress in Reductive Heck Reaction

Yang Xiaomeia, Ma Shaa, Du Yannib, Tao Yunhaib   

  1. a Yunnan University of Traditional Chinese Medicine, Kunming 650500;
    b School of Chemistry Science and Engineering, Yunnan University, Kunming 650091
  • Received:2013-03-31 Revised:2013-05-20 Online:2013-11-25 Published:2013-06-04

还原型Heck反应是不饱和卤代烃与烯烃在Heck反应条件下生成烯烃加成产物的偶联反应. 综述了三十年来还原型Heck反应的研究进展,对还原型Heck反应的方法和催化体系的组成、反应机理、应用和局限性等方面进行了介绍和评价.

关键词: 还原型Heck反应, 钯催化, 配体, 机理, 应用, 进展

Reductive Heck reaction is a coupling reaction which unsaturated halides react with olefinic compounds at the similar Heck conditions to form the addition products. In this paper, the progress in Heck coupling reaction including catalytic systems, mechanism, applications and limitation in organic chemistry is reviewed.

Key words: reductive Heck reaction, palladium catalysis, ligand, mechanism, application, progress