Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (10): 2148-2154.DOI: 10.6023/cjoc201305041 Previous Articles     Next Articles

Articles

基于点击化学合成含有全氟环丁基芳基醚的ABA三嵌段共聚物

李炳臻, 李义和   

  1. 国防科技大学理学院化学与生物学系 长沙 410073
  • 收稿日期:2013-05-26 修回日期:2013-06-19 出版日期:2013-10-25 发布日期:2013-07-03
  • 通讯作者: 李炳臻 E-mail:tylerlibz@gmail.com
  • 基金资助:

    国防科大校预研(No. JC11-02-15)资助项目

Synthesis of Perfluorocyclobutyl Aryl Ether-Containing ABA Triblock Copolymer via Click Chemistry

Li Bingzhen, Li Yihe   

  1. Department of Chemistry and Biology, College of Science, National University of Defense Technology, Changsha 410073
  • Received:2013-05-26 Revised:2013-06-19 Online:2013-10-25 Published:2013-07-03
  • Supported by:

    Project supported by the Advanced Research Project of National University of Defense Technology (No. JC11-02-15).

Because of the unusual polymerization mechanism and normal high polymerization temperature of trifluorovinyl aryl ether monomers, it is difficult to synthesize perfluorocyclobutyl aryl ether (PFCB)-containing block copolymer via sequential addition of monomers. Here a coupling reaction via click chemistry to prepare PFCB-containing ABA triblock copolymer is reported. An azide-ended PFCB polymer, which was firstly prepared by end-modification of methyl-ended PFCB polymer, was coupled with alkynyl-ended polyethylene glycol via the azide alkyne Huisgen cycloaddition.

Key words: block copolymer, end-functionalized group coupling method, click chemistry, perfluorocyclobutyl aryl ether (PFCB)