Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (11): 2435-2439.DOI: 10.6023/cjoc201305053 Previous Articles     Next Articles

Notes

酰胺为氮源的氨化反应及其机理

徐娟, 李加荣, 魏真, 张奇, 史大昕   

  1. 北京理工大学化工与环境学院 北京 100081
  • 收稿日期:2013-06-04 修回日期:2013-06-21 发布日期:2013-07-10
  • 通讯作者: 史大昕 E-mail:shidaxin@bit.edu.cn

Amide as Nitrogen Source: Amination and Mechanism

Xu Juan, Li Jiarong, Wei Zhen, Zhang Qi, Shi Daxin   

  1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081
  • Received:2013-06-04 Revised:2013-06-21 Published:2013-07-10

The mechanism of C—N bond formation with amide as nitrogen source was disclosed. The process included the cleavage of amide C—N bond to form amine and then to construct new C—N bond. With the cooperation of Lewis acid, aryl halides, aryl triflates, boronic acids, aryl siloxanes and azoles could be aminated by amide as nitrogen source.

Key words: amide, nitrogen source, Lewis acid complex of amine, cleavage and formation of C—N bond