Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (4): 630-646.DOI: 10.6023/cjoc201311016 Previous Articles     Next Articles



沈海民a, 武宏科a, 纪红兵b, 史鸿鑫a   

  1. a 浙江工业大学化学工程学院 杭州 310014;
    b 中山大学化学与化学工程学院 广州 510275
  • 收稿日期:2013-11-12 修回日期:2013-12-11 发布日期:2013-12-23
  • 通讯作者: 沈海民
  • 基金资助:

    国家自然科学基金(No. 21306176)和浙江工业大学科研启动基金(No. G2817101103)资助项目.

Progress in the Construction of β-Cyclodextrin-Fe3O4 Supramolecular Systems and Their Application

Shen Haimina, Wu Hongkea, Ji Hongbingb, Shi Hongxina   

  1. a College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014;
    b School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275
  • Received:2013-11-12 Revised:2013-12-11 Published:2013-12-23
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21306176) and the Scientific Research Launching Foundation of Zhejiang University of Technology (No. G2817101103).

The construction and application of β-cyclodextrin-Fe3O4 supramolecular systems at present have been reviewed in detail, especially for the application of β-cyclodextrin-Fe3O4 supramolecular systems constructed covalently in the environmental pollutants adsorption, drug loading and releasing, sensor construction and detection application, separation and catalysis. In all of the section mentioned above, the construction and property of the β-cyclodextrin-Fe3O4 supramolecular systems were discussed systematically which were classified according to the linking groups between β-cyclodextrin and Fe3O4. It was pointed out that the β-cyclodextrin-Fe3O4 supramolecular systems possessed the ability to form inclusion complex with guest molecules, weak catalytic activity and substrate recognition property of β-cyclodextrin unit and the magnetic property of Fe3O4 which could be recovered easily, simultaneously. It was also pointed out that the immobilization of β-cyclodextrin on Fe3O4 nanoparticles to construct heterogeneous β-cyclodextrin-Fe3O4 supramolecular biomimetic catalytic systems will be one of the focus in the construction of nanoscale supramolecular biomimetic catalysts in the future.

Key words: cyclodextrin, Fe3O4, supramolecular systems, construction, application