Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (10): 1992-2000.DOI: 10.6023/cjoc201404022 Previous Articles     Next Articles

Reviews

共价键链杯芳烃-四硫富瓦烯超分子体系研究进展

赵邦屯a, 朱卫民b   

  1. a. 洛阳师范学院化学化工学院 洛阳 471022;
    b. 郑州大学化学与分子工程学院 郑州 450010
  • 收稿日期:2014-04-13 修回日期:2014-05-09 出版日期:2014-10-25 发布日期:2014-06-03
  • 通讯作者: 赵邦屯, 朱卫民 E-mail:zbt@lynu.edu.cn;zhuwm@zzu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos. 21172105,20872058)资助项目

Progress on Covalently Bonded Calixarene-Tetrathiafulvalene Supramolecules

Zhao Bangtuna, Zhu Weiminb   

  1. a. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022;
    b. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001
  • Received:2014-04-13 Revised:2014-05-09 Online:2014-10-25 Published:2014-06-03
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21172105, 20872058).

The main focus of this review is on the supramolecular calixarene-tetrathiafulvalene chemistry. The general aspects of molecular design of calixarene-tetrathiafulvalene systems are reviewed on the attachment of tetrathiafulvalene unit(s) on the calixarene framework through the upper rims or lower rims, and the structually related thiacalixarene and calixpyrroles and so on. This survey is also presented from the view of supamolecular application of calixarene-tetrathiafulvalene systems in electrochemically molecular recognition, ion-mediated electron transfer, molecular assembly, molecular switches and devices etc.

Key words: calixarene, tetrathiafulvalene, molecular recognition, electron transfer, molecular assembly