Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (2): 284-293.DOI: 10.6023/cjoc201409027 Previous Articles     Next Articles

Reviews

铼催化的醇脱羟基反应研究进展

毛国梁a, 贾冰a,b, 王从洋b   

  1. a 石油与天然气化工省重点实验室 东北石油大学化学化工学院 大庆 163318;
    b 北京分子科学国家实验室 中国科学院分子识别与功能重点实验室 中国科学院化学研究所 北京 100190
  • 收稿日期:2014-09-11 修回日期:2014-11-11 出版日期:2015-02-25 发布日期:2014-11-20
  • 通讯作者: 毛国梁, 王从洋 E-mail:mglww001@yahoo.com.cn;wangcy@iccas.ac.cn
  • 基金资助:

    黑龙江省教育厅海外学人科研(No. 1154H14)、黑龙江省教育厅(No. 1154G53)、国家自然科学基金联合基金(No. U1362110)、国家自然科学基金(Nos. 21322203, 21272238)资助项目.

Recent Progress in Re-Catalyzed Dehydroxylation Reactions

Mao Guolianga, Jia Binga,b, Wang Congyangb   

  1. a Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318;
    b Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
  • Received:2014-09-11 Revised:2014-11-11 Online:2015-02-25 Published:2014-11-20
  • Supported by:

    Project supported by the Scientific Research Foundation for Overseas Chinese Scholars of Heilongjiang Province (No. 1154H14), the Department of Education of Heilongjiang Province (No. 1154G53), the Joint Funds of National Natural Science Foundation of China (No. U1362110), and the National Natural Science Foundation of China (Nos. 21322203, 21272238).

The development of novel effective processes for the conversion of abundant renewable resources to fuels and value-added chemicals has spurred new interest in the discovery of selective chemical transformations of polyols and carbohydrates. These compounds have high oxygen content, which is mostly present in the form of hydroxyl groups. Therefore, partial or complete removal of the hydroxyl groups is of great importance. Herein a brief overview on the development of rhenium-catalyzed dehydroxylation reactions in recent years is given, which are roughly classified into two categories: (1) dehydroxylation reactions of monools for new chemical bond formation and (2) dehydroxylation reactions of diols and polyols for olefin syntheses.

Key words: rhenium catalysis, alcohols, dehydroxylation, reductants, olefins