Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (3): 676-680.DOI: 10.6023/cjoc201412047 Previous Articles     Next Articles



王大伟, 余晓丽, 葛冰洋, 苗红艳, 丁玉强   

  1. 江南大学化学与材料工程学院 教育部食品胶体与生物技术重点实验室 无锡 214122
  • 收稿日期:2014-12-29 修回日期:2015-01-26 发布日期:2015-01-28
  • 通讯作者: 王大伟, 丁玉强
  • 基金资助:

    国家自然科学基金(No. 21401080)资助项目.

Synthesis of Sulfonyl Quinone Derivatives by Rh-Catalyzed Sulfonylation of Quinones

Wang Dawei, Yu Xiaoli, Ge Bingyang, Miao Hongyan, Ding Yuqiang   

  1. Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122
  • Received:2014-12-29 Revised:2015-01-26 Published:2015-01-28
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21401080).

The rhodium-catalyzed sulfonylation reaction of quinones with sulfonyl chloride compounds was developed, which provides an efficient and mild method of the synthesis of biologically active sulfonyl quinones with high yields. This methodology is also efficient for the coupling of naphthoquinone with sulfonyl chlorides. The possible reaction mechanism was also proposed.

Key words: rhodium, sulfonylation, cross-coupling, quinones, sulfonyl quinones