Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (7): 1513-1527.DOI: 10.6023/cjoc201601028 Previous Articles     Next Articles



徐光利, 刚芳莉, 董涛生, 傅颖, 杜正银   

  1. 西北师范大学化学化工学院 兰州 730070
  • 收稿日期:2016-01-20 修回日期:2016-03-02 发布日期:2016-03-28
  • 通讯作者: 杜正银
  • 基金资助:


Application of Metal Organic Frameworks in Catalytic Organic Reactions

Xu Guangli, Gang Fangli, Dong Taosheng, Fu Ying, Du Zhengyin   

  1. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou730070
  • Received:2016-01-20 Revised:2016-03-02 Published:2016-03-28
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21262028) and the Natural Science Foundation of Gansu Province (No. 1208RJZA140).

Metal organic frameworks (MOFs) as a new type of organic/inorganic hybrid materials have attracted great focus of scientists in almost twenty years. It is composed of organic ligands and inorganic metal units and generally has a varied topological structure and unique physical/chemical properties. Due to its porous frame structure, large specific surface area and great variety, MOFs are widely used in functional materials, gas adsorption, drug sustained release, catalysis and organic synthesis. It can choose different ligands and metal ions, or change the strategy of synthesis to adjust the size, shape and structure of porous structure. The different ligands can determine the different structure and then affect the properties of MOFs. In this review, the preparation of particular functional MOFs structure and the application of various MOFs in organic synthesis and catalytic organic reactions are reviewed in detail. The summary and prospects about MOFs catalyzed organic reactions and the applications are proposed.

Key words: metal organic frameworks (MOFs), preparation, heterogeneous catalysis, organic synthesis, application