Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (1): 20-30.DOI: 10.6023/cjoc201607017 Previous Articles     Next Articles

REVIEW

苯酚与烯烃的氧化环加成反应研究进展

崔娜, 赵宇, 王云侠   

  1. 西北大学合成与天然功能分子化学教育部重点实验室 化学与材料科学学院 西安 710127
  • 收稿日期:2016-07-10 修回日期:2016-08-30 出版日期:2017-01-25 发布日期:2016-09-08
  • 通讯作者: 王云侠 E-mail:wyx27210@nwu.edu.cn
  • 基金资助:

    陕西省自然科学基金(No. 2011JQ2001)资助项目.

Recent Advances in Oxidative Cycloaddition Reactions of Phenols with Olefins

Cui Na, Zhao Yu, Wang Yunxia   

  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Chemistry & Material Science, Northwest University, Xi'an 710127
  • Received:2016-07-10 Revised:2016-08-30 Online:2017-01-25 Published:2016-09-08
  • Supported by:

    Project supported by the National Natural Science Foundation of Shaanxi Province(No. 2011JQ2001).

Phenol oxidation and the induced transformations can construct various core skeletons of bioactive molecules.Due to the extensive existence of dihydrobenzofuran core,which could be generated from the oxidative cycloaddtion reaction of phenols and olefins in bioactive neolignans and resveratrol oligomers,the oxidative cycloaddition reaction of phenols and olefins catched broad attention from organic chemists.Herein,the progress of oxidative cycloadditon reactions of phenols and olefins in recent years is reviewed according to the difference of reaction conditions,and the corresponding reaction mechanisms are discussed.

Key words: phenol, olefin, oxidative cycloaddition reaction, dihydrobenzofuran