Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (7): 1667-1680.DOI: 10.6023/cjoc201702009 Previous Articles     Next Articles

Special Issue: 热点论文合辑



刘云云, 熊进, 韦丽   

  1. 江西师范大学化学化工学院 南昌 330022
  • 收稿日期:2017-02-09 修回日期:2017-03-16 发布日期:2017-04-01
  • 通讯作者: 刘云云
  • 基金资助:


Recent Advances in the C(sp2)-S Bond Formation Reactions by Transition Metal-Free C(sp2)-H Functionalization

Liu Yunyun, Xiong Jin, Wei Li   

  1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022
  • Received:2017-02-09 Revised:2017-03-16 Published:2017-04-01
  • Contact: 10.6023/cjoc201702009
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No.21562024).

Aryl/vinyl thioethers containing C(sp2)-S bonds are prevalent in biologically relevant molecules and compounds with other potential applications. Around the past decade, rapid progress has taken place in the research area of C(sp2)-S construction, and a large number of efficient new catalytic systems as well as structurally versatile substrates have been identified for such reactions, which significantly enriched the content of the synthetic methodologies on C(sp2)-S bond formation. This review introduces mainly the research advances on transition metal-free C(sp2)-S bond forming reaction by means of C(sp2)-H bond functionalization over the period of 2001~2016.

Key words: transition metal-free, C(sp2)-H bond, (Hetero)aryl, vinyl, C(sp2)-S bond formation