Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine

doi:10.6023/cjoc201702047

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (6): 1392-1397.DOI: 10.6023/cjoc201702047 Previous Articles Next Articles

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三甲基膦支持的硒配位钴氢配合物的合成和性质

栾化鑫, 孙宏建, 薛本静, 李晓燕

山东大学化学与化工学院教育部特种功能聚集体材料重点实验室济南 250199

收稿日期:2017-02-28 修回日期:2017-04-14 发布日期:2017-05-10
通讯作者: 李晓燕 E-mail:xli63@sdu.edu.cn
基金资助:
国家自然科学基金（No.21372143）资助项目.

Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine

Luan Huaxin, Sun Hongjian, Xue Benjing, Li Xiaoyan

Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250199

Received:2017-02-28 Revised:2017-04-14 Published:2017-05-10
Contact: 10.6023/cjoc201702047 E-mail:xli63@sdu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21372143).

1. Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine.PDF(909KB)

Abstract

A mononuclear cobalt(II) complex[Co(4-MeOC₆H₄Se)₂(PMe₃)₃] (1) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SeC₆H₄-2-Me)]₂ (2) were obtained from the reaction of 4-methoxyselenophenol and 2-methylseleno-phenol with Co(PMe₃)₄, respectively. The dicarbonyl cobalt(I) complex[Co(PMe₃)₂(CO)₂(SeC₆H₄-2-Me)] (3) was formed through the reaction of complex 2 with carbon monoxide. A novel selenophenolato hydridocobalt(III) complex[mer-Co(H)(SePh)₂(PMe₃)₃] (4) and a dinuclear cobalt diphenylselenolato complex[Co(PMe₃)₂(SePh)]₂ (5) were synthesized by the reaction of selenophenol with Co(PMe₃)₄. It was found that complex 4 could catalyze the hydrosilylation of aldehydes and ketones. The molecular structures of 1, 3 and 4 were determined by X-ray diffraction.

Key words: hydrido cobalt complex, selenophenol, Se-coordinated, hydrosilylation, carbonyl cobalt complex

Cite this article

Luan Huaxin, Sun Hongjian, Xue Benjing, Li Xiaoyan. Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine[J]. Chin. J. Org. Chem., 2017, 37(6): 1392-1397.

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三甲基膦支持的硒配位钴氢配合物的合成和性质

Synthesis and Properties of a Se-Coordinated Hydrido Cobalt(III) Complex Supported by Trimethylphosphine

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