Progress in Catalysis Transformation of Carbon Dioxide through Hydrosilylation

doi:10.6023/cjoc202210024

Abstract

Reducing carbon dioxide emission and converting carbon dioxide from the air have always been a hot topic for researchers. Carbon dioxide is an ideal raw material for synthesizing organic compounds because of its good physical properties such as non-toxicity, abundance and easy availability. In recent years, hydrosilylation reaction has become an effective method to convert carbon dioxide into formate, formaldehyde, methanol, methane and other valuable chemical products under moderate conditions, which greatly promotes the conversion and utilization of carbon dioxide. The research progress on the design, synthesis and catalytic performance of catalytic systems used to catalyze the hydrosilylation for reduction of carbon dioxide is summarized and discussed. The reaction mechanism of hydrosilylation reduction of carbon dioxide is discussed, and the advantages and disadvantages of various catalyst systems are also analyzed. At last, the future research directions in this field are prospected.

Key words: catalysis, carbon dioxide, hydrosilylation

Cite this article

Zijie Song, Jun Liu, Ying Bai, Jiayun Li, Jiajian Peng. Progress in Catalysis Transformation of Carbon Dioxide through Hydrosilylation[J]. Chinese Journal of Organic Chemistry, 2023, 43(6): 2068-2080.

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Fig. & Tab. 23

Scheme 1. Hydrosilylation of carbon dioxide for methylsilyl formate, bis(methylsilyl)acetal, methoxysilane and methane[1]

Scheme 2. Hydrosilylation of CO2 catalyzed by Ir-NSiN 1[17]

Scheme 3. Hydrosilylation of CO2 catalyzed by Ir-NSiN 2[20]

Scheme 4. Hydrosilylation of CO2 catalyze by iridium complex[22]

Scheme 5. Mechanism of CO2 formylation catalyzed by rhodium complex 4[23]

Scheme 6. Hydrosilylation of CO2 catalyzed by Pd complex 6[25]

Scheme 7. Hydrosilylation of CO2 catalyzed by Pd complex 7[26]

Scheme 8. Insertion of CO2 into the Co—H bond of complex 13[33]

Scheme 9. Mechanism for hydrosilylation of CO2 catalyzedby complex 14[37]

Scheme 10. Mechanism for hydrosilylation CO2 catalyzed by complex 15[38]

Scheme 11. Iron complex catalyzed hydrosilylation of CO2[43]

Scheme 12. Fe catalyzed selective N-methylation and N-formyl- ation of amines with CO2[45]

Scheme 13. Mechanism for hydrosilylation of CO2 catalyzed by complex 16[47]

Scheme 14. Mn-based complex catalytic reduction of CO2 to formamides using amines and PhSiH3[48]

Scheme 15. Possible intermediates in hydrosilylation of CO2 catalyzed by complex 19[52]

Scheme 16. Mechanism for complex 20 actived hydrosilane[53]

Scheme 17. Hydrosilylation of alkyne, benzaldehyde and CO2 catalyzed by [B(C6F5)4] 21, 22 complexes[61]

Scheme 18. Ligand-controlled reduction of CO2 to form methylamines and formamides catalyzed by Cu[66]

Scheme 19. Cu hydrosilylation of CO2 catalyzed by complex 23[67]

Scheme 20. 1,3,2-Diazaphospholene-catalyzed reduction of CO2 to formamides using amines and Ph2SiH2[73]

Scheme 21. TBD-catalyzed synthesis of spiroindoles/spiroindolines from N-aryl-2-alkyltryptamines and CO2 in a one-pot fashion[80]

Scheme 22. Synthesis of p[VBTAm]Cl[86]

Scheme 23. Hydrosilylation of CO2 using silica-supported formate as catalyst [87]

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