Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (10): 3544-3557.DOI: 10.6023/cjoc202306009 Previous Articles     Next Articles

Special Issue: 有机硅化学专辑-2023


冯向青a, 杜海峰a,b,*()   

  1. a 中国科学院化学研究所 中国科学院分子识别与功能重点实验室 北京 100190
    b 中国科学院大学 北京 100049
  • 收稿日期:2023-06-12 修回日期:2023-07-22 发布日期:2023-08-16
  • 基金资助:

B(C6F5)3-Catalyzed Silylation of Unsaturated Hydrocarbons

Xiangqing Fenga, Haifeng Dua,b()   

  1. a CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
    b University of Chinese Academy of Sciences, Beijing 100049
  • Received:2023-06-12 Revised:2023-07-22 Published:2023-08-16
  • Contact: *E-mail:
  • Supported by:
    National Natural Science Foundation of China(21825108)

Organosilicon compounds have been widely applied in synthetic chemistry, medicinal chemistry, polymer chemistry, organic photoelectric materials and other fields due to their unique properties. The silylation of unsaturated compounds represents one of the most important approaches for the synthesis of organosilicon compounds, which has attracted the intensive attention of chemists, and a great success has been achieved. As a unique non-metallic Lewis acid, B(C6F5)3-catalyzed silylation of unsaturated compounds has made a significant progress in recent years. This subject and the corresponding mechanism are demonstrated.

Key words: Lewis acids, silylation reaction, hydrosilylation reaction, unsaturated hydrocarbons