Synthesis and Application of N-Cyclopalladated Ferrocene Derivatives

doi:10.6023/cjoc201707019

Abstract

Progress in the synthesis and application of the cyclopalladated derivatives of ferrocene with a donor nitrogen atom in the directing group is surveyed including the planar chirality and enantioselective catalysis of organic reactions and rearrangements. Transannular palladation has been found giving achiral 1,1'-disubstituted ferrocenes of ansa-structure. Cyclopalladated ferrocenes have been widely used as catalysts in the cross-coupling reactions (Suzuki, Heck, aza-Claisen, etc. )

Key words: cyclopalladation, ferrocenyl amines, ferrocenyl imines, enantioselectivity, cross-coupling reactions, Heck reaction, Suzuki reaction, aza-Claisen rearrangement

Cite this article

Sokolov Viacheslav I.. Synthesis and Application of N-Cyclopalladated Ferrocene Derivatives[J]. Chin. J. Org. Chem., 2018, 38(1): 75-85.

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