Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (1): 75-85.DOI: 10.6023/cjoc201707019 Previous Articles     Next Articles

Special Issue: 庆祝吴养洁院士九十华诞专辑

Reviews

N-环钯化二茂铁衍生物的合成和应用(英文)

Viacheslav I. Sokolov   

  1. 俄罗斯科学院有机化合物研究所 莫斯科 119991
  • 收稿日期:2017-07-17 修回日期:2017-09-06 出版日期:2018-01-25 发布日期:2017-10-11
  • 通讯作者: Viacheslav I. Sokolov E-mail:sokol@ineos.ac.ru
  • 基金资助:

    Project support by the Russian Foundation for Basic Research (No. 14-03-00467).

Synthesis and Application of N-Cyclopalladated Ferrocene Derivatives

Sokolov Viacheslav I.   

  1. Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation
  • Received:2017-07-17 Revised:2017-09-06 Online:2018-01-25 Published:2017-10-11
  • Contact: 10.6023/cjoc201707019 E-mail:sokol@ineos.ac.ru
  • Supported by:

    Project support by the Russian Foundation for Basic Research (No. 14-03-00467).

Progress in the synthesis and application of the cyclopalladated derivatives of ferrocene with a donor nitrogen atom in the directing group is surveyed including the planar chirality and enantioselective catalysis of organic reactions and rearrangements. Transannular palladation has been found giving achiral 1,1'-disubstituted ferrocenes of ansa-structure. Cyclopalladated ferrocenes have been widely used as catalysts in the cross-coupling reactions (Suzuki, Heck, aza-Claisen, etc. )

Key words: cyclopalladation, ferrocenyl amines, ferrocenyl imines, enantioselectivity, cross-coupling reactions, Heck reaction, Suzuki reaction, aza-Claisen rearrangement